An efficient and economical process for lignin depolymerization in biomass-derived solvent tetrahydrofuran
文献类型：期刊论文
| 作者 | Long, Jinxing; Zhang, Qi; Wang, Tiejun; Zhang, Xinghua; Xu, Ying; Ma, Longlong |
| 刊名 | bioresource technology
 |
| 出版日期 | 2014-02-01 |
| 卷号 | 154页码:10-17 |
| 关键词 | Lignin Phenolic monomer Tetrahydrofuran MgO Depolymerization |
| 英文摘要 | the depolymerization of renewable lignin for phenolic monomer, a versatile biochemical and precursor for biofuel, has attracted increasing attention. here, an efficient base-catalyzed depolymerization process for this natural aromatic polymer is presented with cheap industrial solid alkali mgo and biomass-derived solvent tetrahydrofuran (thf). results showed that more than 13.2% of phenolic monomers were obtained under 250 degrees c for 15 min, because of the excellent lignin dissolution of thf and its promotion effect on the catalytic activity of mgo. furthermore, comparison characterization on the raw material, products and residual solid using elemental analysis, ft-ir, tg-dsc, py-gc-ms and chemo-physical absorption and desorption demonstrated that this base-catalyzed process can inhibit char formation significantly. whereas, the fact that thermal repolymerization of oligomer on the pore and surface of catalyst resulting in the declination of the catalytic performance is responsible for the residue formation. (c) 2013 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; life sciences & biomedicine ; technology |
| 类目[WOS] | agricultural engineering ; biotechnology & applied microbiology ; energy & fuels |
| 研究领域[WOS] | agriculture ; biotechnology & applied microbiology ; energy & fuels |
| 关键词[WOS] | chemicals ; degradation ; conversion ; catalysts ; bagasse |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000331461600002 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/10767]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Long, Jinxing,Zhang, Qi,Wang, Tiejun,et al. An efficient and economical process for lignin depolymerization in biomass-derived solvent tetrahydrofuran[J]. bioresource technology,2014,154:10-17. |
| APA | Long, Jinxing,Zhang, Qi,Wang, Tiejun,Zhang, Xinghua,Xu, Ying,&Ma, Longlong.(2014).An efficient and economical process for lignin depolymerization in biomass-derived solvent tetrahydrofuran.bioresource technology,154,10-17. |
| MLA | Long, Jinxing,et al."An efficient and economical process for lignin depolymerization in biomass-derived solvent tetrahydrofuran".bioresource technology 154(2014):10-17. |
入库方式： OAI收割
来源：广州能源研究所
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