La1-xSrxFeO3 perovskites as oxygen carriers for the partial oxidation of methane to syngas
文献类型：期刊论文
| 作者 | Zhao, Kun1,2 ; He, Fang1; Huang, Zhen1; Zheng, Anqing1; Li, Haibin1; Zhao, Zengli1
|
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2014-07-01 |
| 卷号 | 35期号:7页码:1196-1205 |
| 关键词 | Perovskite Lattice oxygen Thermogravimetric redox Partial oxidation Syngas |
| 英文摘要 | we prepared perovskite-type oxides la1-xsrxfeo3 (x = 0, 0.3, 0.5, 0.9) by a combustion method and used these as oxygen carriers for the partial oxidation of methane. x-ray diffration, scanning electron microscopy and h-2 temperature-programmed reduction techniques were used to characterize the samples. their reduction and oxidation activities were investigated using a thermogravimetric analysis reactor and fixed-bed reaction equipment, respectively. the results showed that the lattice oxygen in la1-xsrxfeo3 was suitable for the partial oxidation of methane to produce syngas. their capacity to provide oxygen was enhanced by the partial substitution of la3+ by sr2+ and the synthesized materials have good regenerability. the optimal degree of sr substitution was found to be x = 0.3-0.5 for la1-xsrxfeo3 with regard to reactivity, selectivity, and oxygen-donating ability. ch4 conversion was higher than 70%, and the n(h-2)/n(co) ratio remained about 2:1 and no obvious decomposition of ch4 occurred. (c) 2014, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | chemical-looping combustion ; synthesis gas ; lattice oxygen ; bed reactor ; hydrogen ; oxides ; fe ; cu |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000338913700027 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/10771]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Kun,He, Fang,Huang, Zhen,et al. La1-xSrxFeO3 perovskites as oxygen carriers for the partial oxidation of methane to syngas[J]. chinese journal of catalysis,2014,35(7):1196-1205. |
| APA | Zhao, Kun,He, Fang,Huang, Zhen,Zheng, Anqing,Li, Haibin,&Zhao, Zengli.(2014).La1-xSrxFeO3 perovskites as oxygen carriers for the partial oxidation of methane to syngas.chinese journal of catalysis,35(7),1196-1205. |
| MLA | Zhao, Kun,et al."La1-xSrxFeO3 perovskites as oxygen carriers for the partial oxidation of methane to syngas".chinese journal of catalysis 35.7(2014):1196-1205. |
入库方式： OAI收割
来源：广州能源研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。