Phase equilibrium conditions for simulated landfill gas hydrate formation in aqueous solutions of tetrabutylammonium nitrate
文献类型：期刊论文
| 作者 | Shi, Ling-Li1,2; Liang, De-Qing1; Li, Dong-Liang1 |
| 刊名 | journal of chemical thermodynamics
 |
| 出版日期 | 2014 |
| 卷号 | 68页码:322-326 |
| 关键词 | Clathrate hydrate, Phase equilibrium Methane Carbon dioxide Tetrabutylammonium nitrate |
| 英文摘要 | hydrate phase equilibrium conditions for the simulated landfill gas (lfg) of methane and carbon dioxide (50 mol% methane, 50 mol% carbon dioxide) were investigated with the pressure range of (1.90 to 13.83) mpa and temperature range of (280.0 to 288.3) k at (0.050, 0.170, 0.340, and 0.394) mass fraction (w) of tetrabutylammonium nitrate (tbano(3)). the phase boundary between liquid-vapor-hydrate (l-v-h) phases and liquid-vapor (l-v) phases was determined by employing an isochoric pressure-search method. the phase equilibrium data measured showed that tbano3 appeared a remarkable promotion effect at w(tbano3) = 0.394, corresponding to tbano(3) center dot 26h(2)o, but inhibition effect at w(tbano3) = (0.050, or 0.170) on the semiclathrate hydrate formation. in addition, the application of tbano(3) at 0.340 mass fraction, corresponding to tbano(3) center dot 32h(2)o, displayed promotion effect at lower pressures (below 6.38 mpa) and inhibition effect at higher pressures (above 6.38 mpa). (c) 2013 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | thermodynamics ; chemistry, physical |
| 研究领域[WOS] | thermodynamics ; chemistry |
| 关键词[WOS] | butyl ammonium bromide ; semi-clathrate hydrate ; carbon-dioxide ; dissociation enthalpies ; semiclathrate hydrate ; co2 capture ; plus water ; methane ; hydrogen ; tbab |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000326271100042 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/10779]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, Ling-Li,Liang, De-Qing,Li, Dong-Liang. Phase equilibrium conditions for simulated landfill gas hydrate formation in aqueous solutions of tetrabutylammonium nitrate[J]. journal of chemical thermodynamics,2014,68:322-326. |
| APA | Shi, Ling-Li,Liang, De-Qing,&Li, Dong-Liang.(2014).Phase equilibrium conditions for simulated landfill gas hydrate formation in aqueous solutions of tetrabutylammonium nitrate.journal of chemical thermodynamics,68,322-326. |
| MLA | Shi, Ling-Li,et al."Phase equilibrium conditions for simulated landfill gas hydrate formation in aqueous solutions of tetrabutylammonium nitrate".journal of chemical thermodynamics 68(2014):322-326. |
入库方式： OAI收割
来源：广州能源研究所
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