Efficient and product-controlled depolymerization of lignin oriented by metal chloride cooperated with Pd/C
文献类型：期刊论文
| 作者 | Shu, Riyang1,2; Long, Jinxing1; Yuan, Zhengqiu1,2; Zhang, Qi1 ; Wang, Tiejun1; Wang, Chenguang1; Ma, Longlong1
|
| 刊名 | bioresource technology
 |
| 出版日期 | 2015-03-01 |
| 卷号 | 179页码:84-90 |
| 关键词 | Lignin Product-controlled Guaiacols Phenols Phenolic monomer |
| 英文摘要 | an efficient lignin depolymerization process with highly controllable product distribution was presented using metal chloride (mclx) cooperated with pd/c. the catalytic performances of mclx were investigated. the effect of reaction conditions on the lignin depolymerization and products distribution were also studied. results showed that more than 35.4% yield of phenolic monomer including 7.8% phenols and 1.1% guaiacols could be obtained under optimized condition. and the product distribution can be efficiently controlled by the modification of the metal cation through different pathway of lewis acid catalysis and coordination catalysis. furthermore, the pd/c catalyst showed an excellent recyclability, where no significant loss of the catalytic activity was exhibited after 3 runs. moreover, the product control mechanism was proposed. (c) 2014 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; life sciences & biomedicine ; technology |
| 类目[WOS] | agricultural engineering ; biotechnology & applied microbiology ; energy & fuels |
| 研究领域[WOS] | agriculture ; biotechnology & applied microbiology ; energy & fuels |
| 关键词[WOS] | ionic liquid ; model compounds ; catalysts ; conversion ; chemicals ; hydrodeoxygenation ; hydrogenolysis ; biomass ; valorization ; liquefaction |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000348041600013 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/10794]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shu, Riyang,Long, Jinxing,Yuan, Zhengqiu,et al. Efficient and product-controlled depolymerization of lignin oriented by metal chloride cooperated with Pd/C[J]. bioresource technology,2015,179:84-90. |
| APA | Shu, Riyang.,Long, Jinxing.,Yuan, Zhengqiu.,Zhang, Qi.,Wang, Tiejun.,...&Ma, Longlong.(2015).Efficient and product-controlled depolymerization of lignin oriented by metal chloride cooperated with Pd/C.bioresource technology,179,84-90. |
| MLA | Shu, Riyang,et al."Efficient and product-controlled depolymerization of lignin oriented by metal chloride cooperated with Pd/C".bioresource technology 179(2015):84-90. |
入库方式： OAI收割
来源：广州能源研究所
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