Organosilicon functionalized glycerol carbonates as electrolytes for lithium-ion batteries
文献类型：期刊论文
| 作者 | Wang, Jinglun1 ; Yong, Tianqiao1,2; Yang, Jianwen3; Ouyang, Chuying4; Zhang, Lingzhi1
|
| 刊名 | rsc advances
 |
| 出版日期 | 2015 |
| 卷号 | 5期号:23页码:17660-17666 |
| 英文摘要 | two triethoxyl-/trimethoxyl-silyl functionalized glycerol carbonates and one disiloxanyl functionalized glycerol carbonate were synthesized through a cycloaddition reaction of carbon dioxide with allyl glycidyl ether followed by a hydrosilylation with the corresponding hydrosilanes. their chemical structures were fully characterized by h-1 and c-13 nuclear magnetic resonance (nmr) spectroscopy and their basic physicochemical properties including dielectric constant, viscosity, ionic conductivity, apparent lithium transference number and electrochemical window, were systematically measured. trimethoxysilyl functionalized glycerol carbonate as electrolyte solvent with lipf6 (0.6 m) and lithium oxalyldifluoroborate (0.4 m) binary salts exhibited good cycling stability over 2.7-4.4 v in high-voltage-licoo2/graphite full cells. disiloxane functionalized glycerol carbonate acted as an efficient electrolyte additive to improve the wetting property on the separator in li/licoo2 cells. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | vinyl ethylene carbonate ; cells ; additives ; solvents ; surface ; liquid ; performance ; electrodes ; stability ; silane |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000349557400038 |
| 源URL | [http://ir.giec.ac.cn/handle/344007/10799]  |
| 专题 | 中国科学院广州能源研究所 |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 3.Guilin Univ Technol, Coll Chem & Bioengn, Guilin 541004, Guangxi, Peoples R China 4.Jiangxi Normal Univ, Dept Phys, Nanchang 330022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Jinglun,Yong, Tianqiao,Yang, Jianwen,et al. Organosilicon functionalized glycerol carbonates as electrolytes for lithium-ion batteries[J]. rsc advances,2015,5(23):17660-17666. |
| APA | Wang, Jinglun,Yong, Tianqiao,Yang, Jianwen,Ouyang, Chuying,&Zhang, Lingzhi.(2015).Organosilicon functionalized glycerol carbonates as electrolytes for lithium-ion batteries.rsc advances,5(23),17660-17666. |
| MLA | Wang, Jinglun,et al."Organosilicon functionalized glycerol carbonates as electrolytes for lithium-ion batteries".rsc advances 5.23(2015):17660-17666. |
入库方式： OAI收割
来源：广州能源研究所
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