Curtius-like Rearrangement of an Iron-Nitrenoid Complex and Application in Biomimetic Synthesis of Bisindolylmethanes
文献类型：期刊论文
| 作者 | Li, Dashan1,3; Wu, Ting1,3; Lang, Kangjiang1,3; Xia, Chengfeng1,2 |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2016-05-06 |
| 卷号 | 18期号:9页码:2228-2231 |
| 英文摘要 | A Curtius-like rearrangement of hydroxamates to isocyanates was discovered. This reaction was initiated from an iron(II)-nitrenoid complex, which was generated by the iron(II)-catalyzed cleavage of N-O bonds of functionalized hydroxamates. To demonstrate the efficiency of this new Curtius-like rearrangement in synthetic chemistry, a biomimetic strategy for the one-pot preparation of bisindolylmethanes was developed. |
| 类目[WOS] | Chemistry, Organic |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | LOSSEN REARRANGEMENT ; CARBOXYLIC-ACIDS ; PROSTATE-CANCER ; INTRAMOLECULAR AMINOHYDROXYLATION ; FUNCTIONALIZED HYDROXYLAMINES ; HYDROXAMIC ACIDS ; ARSINDOLINE B ; INDOLES ; DERIVATIVES ; GROWTH |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000375891700072 |
| 源URL | [http://ir.kib.ac.cn/handle/151853/26247]  |
| 专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Peoples R China 2.Yunnan Univ, Key Lab Med Chem Nat Resources, Minist Educ, Kunming 650091, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Dashan,Wu, Ting,Lang, Kangjiang,et al. Curtius-like Rearrangement of an Iron-Nitrenoid Complex and Application in Biomimetic Synthesis of Bisindolylmethanes[J]. ORGANIC LETTERS,2016,18(9):2228-2231. |
| APA | Li, Dashan,Wu, Ting,Lang, Kangjiang,&Xia, Chengfeng.(2016).Curtius-like Rearrangement of an Iron-Nitrenoid Complex and Application in Biomimetic Synthesis of Bisindolylmethanes.ORGANIC LETTERS,18(9),2228-2231. |
| MLA | Li, Dashan,et al."Curtius-like Rearrangement of an Iron-Nitrenoid Complex and Application in Biomimetic Synthesis of Bisindolylmethanes".ORGANIC LETTERS 18.9(2016):2228-2231. |
入库方式： OAI收割
来源：昆明植物研究所
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