Unusual adamantane type polyprenylated acylphloroglucinols with an oxirane unit and their structural transformation from Hypericum hookerianum
文献类型:期刊论文
作者 | Ye, Ye1,2; Yang, Xing-Wei1![]() ![]() |
刊名 | TETRAHEDRON
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出版日期 | 2016-06-02 |
卷号 | 72期号:22页码:3057-3062 |
关键词 | Polyprenylated acylphloroglucinol Hypericum hookerianum Hookeriones A-H Adamantane Oxirane |
英文摘要 | Hookeriones A-D (1-4), adamantane type polycyclic polyprenylated acylphloroglucinols (PPAPs), and hookeriones E-H (5-8), 1,9-seco-adamantane type PPAPs, were isolated from Hypericum hookerianum, along with six known analogues. The structures of 1-8, sharing a common 28,29-epoxide moiety, were determined on the basis of comprehensive NMR and MS spectroscopic data. The biomimetic synthesis of 5-7 from the biogenetically precursors 1-3 was performed, respectively. Absolute configurations of these new PPAPs were further defined by electronic circular dichroism (ECD) and biomimetic synthesis methods. (C) 2016 Published by Elsevier Ltd. |
类目[WOS] | Chemistry, Organic |
研究领域[WOS] | Chemistry |
关键词[WOS] | ANTITUMOR-ACTIVITY ; DERIVATIVES ; HYPERFORIN ; SAMPSONII ; SKELETON ; HENRYI ; CORES ; TUMOR ; MICE ; STEM |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000376703700041 |
源URL | [http://ir.kib.ac.cn/handle/151853/26262] ![]() |
专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
作者单位 | 1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, Kunming 650201, Yunnan, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Ye, Ye,Yang, Xing-Wei,Xu, Gang. Unusual adamantane type polyprenylated acylphloroglucinols with an oxirane unit and their structural transformation from Hypericum hookerianum[J]. TETRAHEDRON,2016,72(22):3057-3062. |
APA | Ye, Ye,Yang, Xing-Wei,&Xu, Gang.(2016).Unusual adamantane type polyprenylated acylphloroglucinols with an oxirane unit and their structural transformation from Hypericum hookerianum.TETRAHEDRON,72(22),3057-3062. |
MLA | Ye, Ye,et al."Unusual adamantane type polyprenylated acylphloroglucinols with an oxirane unit and their structural transformation from Hypericum hookerianum".TETRAHEDRON 72.22(2016):3057-3062. |
入库方式: OAI收割
来源:昆明植物研究所
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