Nickel Catalyzed Conversion of Cyclohexanol into Cyclohexylamine in Water and Low Boiling Point Solvents
文献类型：期刊论文
| 作者 | Qi, Yunfei1,2; Yu, Haiyun1; Cao, Quan2 ; Dong, Bo2; Mu, Xindong2; Mao, Aiqing1
|
| 刊名 | CATALYSTS
 |
| 出版日期 | 2016-05-01 |
| 卷号 | 6期号:5 |
| 关键词 | nickel cyclohexanol cyclohexylamine base hydrogen |
| 英文摘要 | Nickel is found to demonstrate high performance in the amination of cyclohexanol into cyclohexylamine in water and two solvents with low boiling points: tetrahydrofuran and cyclohexane. Three catalysts, Raney Ni, Ni/Al2O3 and Ni/C, were investigated and it is found that the base, hydrogen, the solvents and the support will affect the activity of the catalyst. In water, all the three catalysts achieved over 85% conversion and 90% cyclohexylamine selectivity in the presence of base and hydrogen at a high temperature. In tetrahydrofuran and cyclohexane, Ni/Al2O3 exhibits better activity than Ni/C under optimal conditions. Ni/C was stable during recycling in aqueous ammonia, while Ni/Al2O3 was not due to the formation of AlO(OH). |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | PRIMARY AMINES ; REDUCTIVE AMINATION ; SECONDARY ALCOHOLS ; AMMONIA |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000377260900004 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/8226]  |
| 专题 | 青岛生物能源与过程研究所_绿色化学催化团队 |
| 作者单位 | 1.Anhui Univ Technol, Sch Mat Sci & Engn, Key Lab Mat Sci & Proc Anhui Prov, Maanshan 243002, Anhui, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biobased Mat, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qi, Yunfei,Yu, Haiyun,Cao, Quan,et al. Nickel Catalyzed Conversion of Cyclohexanol into Cyclohexylamine in Water and Low Boiling Point Solvents[J]. CATALYSTS,2016,6(5). |
| APA | Qi, Yunfei,Yu, Haiyun,Cao, Quan,Dong, Bo,Mu, Xindong,&Mao, Aiqing.(2016).Nickel Catalyzed Conversion of Cyclohexanol into Cyclohexylamine in Water and Low Boiling Point Solvents.CATALYSTS,6(5). |
| MLA | Qi, Yunfei,et al."Nickel Catalyzed Conversion of Cyclohexanol into Cyclohexylamine in Water and Low Boiling Point Solvents".CATALYSTS 6.5(2016). |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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