Properties of nanocellulose isolated from corncob residue using sulfuric acid, formic acid, oxidative and mechanical methods
文献类型:期刊论文
作者 | Liu, Chao1,2![]() ![]() ![]() ![]() ![]() |
刊名 | CARBOHYDRATE POLYMERS
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出版日期 | 2016-10-20 |
卷号 | 151页码:716-724 |
关键词 | Corncob residue Nanocellulose Formic acid hydrolysis PFI refining Cellulose nanocrystals Cellulose nanofibrils |
英文摘要 | In this work, nanocellulose was extracted from bleached corncob residue (CCR), an underutilized lignocellulose waste from furfural industry, using four different methods (i.e. sulfuric acid hydrolysis, formic acid (FA) hydrolysis, 2,2,6,6-tetramethylpiperidine-l-oxyl (TEMPO)-mediated oxidation, and pulp refining, respectively). The self-assembled structure, morphology, dimension, crystallinity, chemical structure and thermal stability of prepared nanocellulose were investigated. FA hydrolysis produced longer cellulose nanocrystals (CNCs) than the one obtained by sulfuric acid hydrolysis, and resulted in high crystallinity and thermal stability due to its preferential degradation of amorphous cellulose and lignin. The cellulose nanofibrils (CNFs) with fine and individualized structure could be isolated by TEMPO -mediated oxidation. In comparison with other nanocellulose products, the intensive pulp refining led to the CNFs with the longest length and the thickest diameter. This comparative study can help to provide an insight into the utilization of CCR as a potential source for nanocellulose production. (C) 2016 Elsevier Ltd. All rights reserved. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Applied ; Chemistry, Organic ; Polymer Science |
研究领域[WOS] | Chemistry ; Polymer Science |
关键词[WOS] | CELLULOSE NANOCRYSTALS ; NANOFIBRILLATED CELLULOSE ; ENZYMATIC SACCHARIFICATION ; LIGNOCELLULOSIC BIOMASS ; SULFATE GROUPS ; NANOCOMPOSITES ; HYDROLYSIS ; PAPER ; WOOD ; NANOFIBERS |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000380943900082 |
源URL | [http://ir.qibebt.ac.cn/handle/337004/8428] ![]() |
专题 | 青岛生物能源与过程研究所_绿色化学催化团队 |
作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Tianjin Univ Sci & Technol, Coll Papermaking Sci & Technol, Tianjin Key Lab Pulp & Paper, Tianjin 300457, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Chao,Li, Bin,Du, Haishun,et al. Properties of nanocellulose isolated from corncob residue using sulfuric acid, formic acid, oxidative and mechanical methods[J]. CARBOHYDRATE POLYMERS,2016,151:716-724. |
APA | Liu, Chao.,Li, Bin.,Du, Haishun.,Lv, Dong.,Zhang, Yuedong.,...&Peng, Hui.(2016).Properties of nanocellulose isolated from corncob residue using sulfuric acid, formic acid, oxidative and mechanical methods.CARBOHYDRATE POLYMERS,151,716-724. |
MLA | Liu, Chao,et al."Properties of nanocellulose isolated from corncob residue using sulfuric acid, formic acid, oxidative and mechanical methods".CARBOHYDRATE POLYMERS 151(2016):716-724. |
入库方式: OAI收割
来源:青岛生物能源与过程研究所
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