中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Renewable chemical feedstocks from peanut shell liquefaction: Preparation and characterization of liquefied products and residue

文献类型:期刊论文

作者Zhang, Qinqin1; Zhang, Guangyu1; Han, Dezhi2; Wu, Yumin1
刊名JOURNAL OF APPLIED POLYMER SCIENCE
出版日期2016-11-20
卷号133期号:44
关键词cellulose and other wood products degradation properties and characterization recycling
英文摘要The objective of this investigation is to liquefy peanut shell for the preparation of aromatic polyol-rich products. The influences of reaction parameters are discussed. It is found that, compared to single-solvent, the mixture of polyethylene glycol and glycerol as solvents shows higher liquefaction efficiency. And the maximum liquefaction yield of 98.7 wt % can be achieved when the sulfuric acid content, mass ratio between polyethylene glycerol, glycerol, and peanut shell powder, liquefaction temperature, and time are 17 wt % (relative to peanut shell), 8/2/1, 150 degrees C, and 2 h, respectively. Furthermore, the solubility test result indicates that the liquefied products are fully soluble in the water and polyol. Meanwhile, the properties of the peanut shell and liquefaction residue were analyzed by means of attenuated total reflectance-Fourier transform infrared spectroscope, thermal gravity analysis, and scanning electron microscope. The polysaccharide is degraded by the cleaving of C-O bond, and the lignin is decomposed by leaving the dominant linkages including beta-O-4, 4-O-5, and dibenzodioxocin units. The fibers in the peanut shell are broken, and the nondegraded components in the residue lost their network structure. (C) 2016 Wiley Periodicals, Inc.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Polymer Science
研究领域[WOS]Polymer Science
关键词[WOS]POLYURETHANE FOAMS ; RAPID LIQUEFACTION ; ETHYLENE-GLYCOL ; CRUDE GLYCEROL ; WHEAT-STRAW ; LIGNIN ; BIOMASS ; WOOD ; BIOPOLYOLS ; ALCOHOL
收录类别SCI
语种英语
WOS记录号WOS:000383356200025
源URL[http://ir.qibebt.ac.cn/handle/337004/8528]  
专题青岛生物能源与过程研究所_热化学转化事业部
作者单位1.Qingdao Univ Sci & Technol, Coll Chem Engn, Qingdao 266042, Peoples R China
2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Biofuels, Qingdao 266101, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Qinqin,Zhang, Guangyu,Han, Dezhi,et al. Renewable chemical feedstocks from peanut shell liquefaction: Preparation and characterization of liquefied products and residue[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2016,133(44).
APA Zhang, Qinqin,Zhang, Guangyu,Han, Dezhi,&Wu, Yumin.(2016).Renewable chemical feedstocks from peanut shell liquefaction: Preparation and characterization of liquefied products and residue.JOURNAL OF APPLIED POLYMER SCIENCE,133(44).
MLA Zhang, Qinqin,et al."Renewable chemical feedstocks from peanut shell liquefaction: Preparation and characterization of liquefied products and residue".JOURNAL OF APPLIED POLYMER SCIENCE 133.44(2016).

入库方式: OAI收割

来源:青岛生物能源与过程研究所

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