A ribbon-like ultramicroporous conjugated polycarbazole network for gas storage and separation
文献类型：期刊论文
| 作者 | Qiao, Shanlin1,2; Wei, Huan1; Wang, Ting2; Huang, Wei2; Gu, Chunyang2; Yang, Renqiang2; Li, Xiaoyun1 |
| 刊名 | NEW JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2016 |
| 卷号 | 40期号:4页码:3172-3176 |
| 英文摘要 | A new ultramicroporous conjugated network, P-TCzTAT, enriched with propeller-like carbazole building blocks was designed and synthesized by FeCl3 oxidative coupling polymerization at room temperature. The adsorption isotherm of N-2 reveals that the polymer features a high Brunauer-Emmett-Teller (BET) specific surface area of 1028 m(2) g(-1) and a predominantly narrow pore width of 0.54 nm. The ultramicroporous polymer has strong affinity for CO2, with high sorption abilities of 18.15% at 273 K and 1.1 bar and 10.69% at 273 K/1.1 bar and 298 K/1.1 bar, which can be ascribed to not only its optimal fraction of ultramicropores but also its high nitrogen content derived from the carbazole components. P-TCzTAT also exhibited potential application in gas storage and in CO2/CH4 and CO2/N-2 gas separation. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | COVALENT ORGANIC FRAMEWORKS ; SURFACE-AREA ; CO2 CAPTURE ; CARBON-DIOXIDE ; MICROPOROUS POLYMERS ; ENERGY APPLICATIONS ; HYDROGEN STORAGE ; ACTIVATED CARBON ; PORE-SIZE ; ADSORPTION |
| 收录类别 | SCI ; IC |
| 语种 | 英语 |
| WOS记录号 | WOS:000373993600027 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/8261]  |
| 专题 | 青岛生物能源与过程研究所_先进有机功能材料团队 |
| 作者单位 | 1.Hebei Univ Sci & Technol, Inst Chem Ind & Pharmaceut Engn, Shijiazhuang 050000, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qiao, Shanlin,Wei, Huan,Wang, Ting,et al. A ribbon-like ultramicroporous conjugated polycarbazole network for gas storage and separation[J]. NEW JOURNAL OF CHEMISTRY,2016,40(4):3172-3176. |
| APA | Qiao, Shanlin.,Wei, Huan.,Wang, Ting.,Huang, Wei.,Gu, Chunyang.,...&Li, Xiaoyun.(2016).A ribbon-like ultramicroporous conjugated polycarbazole network for gas storage and separation.NEW JOURNAL OF CHEMISTRY,40(4),3172-3176. |
| MLA | Qiao, Shanlin,et al."A ribbon-like ultramicroporous conjugated polycarbazole network for gas storage and separation".NEW JOURNAL OF CHEMISTRY 40.4(2016):3172-3176. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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