中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis of multi-armed small molecules with planar terminals and their application in organic solar cells

文献类型:期刊论文

作者Dang, Dongfeng1,2; Zhou, Pei1; Xiao, Manjun1,3; Yang, Renqiang3; Zhu, Weiguo1
刊名DYES AND PIGMENTS
出版日期2016-10-01
卷号133页码:1-8
关键词Organic solar cells D-A type small molecules Planar terminals Multi-armed small molecules 3D molecules
英文摘要Bi-armed Cz(BT-T-3Cz)(2), tri-armed TPA(BT-T-3Cz)(3) and tetra-armed SF(BT-T-3Cz)(4) with planar terminals were designed, in which carbazole, triphenylamine and spiro-fluorene units were employed as the electron-rich core, respectively, and benzothiadiazole units were introduced as the electron-deficient arms. As displayed, when the electron-deficient arms in molecules increase, improved thermal properties and increased extinction coefficient were obtained. Also as anticipated, the spatial configurations of SMs could affect their photovoltaic performance significantly. The linear Cz(BT-T-3Cz)(2)-based solar cells exhibited a PCE value of 3.0%, however, tri-armed TPA(BT-T-3Cz)(3) and tetra-armed SF(BT-T-3Cz)(4) displayed better photovoltaic properties with the PCE values up to 5.25% and 4.37% in their corresponding devices, respectively, indicating that altering the spatial configurations in molecules is an efficient method to enhance their photovoltaic performance in OSCs. (C) 2016 Elsevier Ltd. All rights reserved.
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Engineering, Chemical ; Materials Science, Textiles
研究领域[WOS]Chemistry ; Engineering ; Materials Science
关键词[WOS]STAR-SHAPED MOLECULES ; PHOTOVOLTAIC PERFORMANCE ; BAND-GAP ; CONJUGATED POLYMERS ; TRIPHENYLAMINE CORE ; SIDE-CHAINS ; DONOR ; COPOLYMERS ; EFFICIENCY ; SYSTEMS
收录类别SCI
语种英语
WOS记录号WOS:000381844500001
源URL[http://ir.qibebt.ac.cn/handle/337004/8497]  
专题青岛生物能源与过程研究所_先进有机功能材料团队
作者单位1.Xiangtan Univ, Minist Educ, Key Lab Environm Friendly Chem & Applicat, Dept Chem, Xiangtan 411105, Peoples R China
2.Xi An Jiao Tong Univ, Sch Sci, Xian 710049, Peoples R China
3.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
推荐引用方式
GB/T 7714
Dang, Dongfeng,Zhou, Pei,Xiao, Manjun,et al. Synthesis of multi-armed small molecules with planar terminals and their application in organic solar cells[J]. DYES AND PIGMENTS,2016,133:1-8.
APA Dang, Dongfeng,Zhou, Pei,Xiao, Manjun,Yang, Renqiang,&Zhu, Weiguo.(2016).Synthesis of multi-armed small molecules with planar terminals and their application in organic solar cells.DYES AND PIGMENTS,133,1-8.
MLA Dang, Dongfeng,et al."Synthesis of multi-armed small molecules with planar terminals and their application in organic solar cells".DYES AND PIGMENTS 133(2016):1-8.

入库方式: OAI收割

来源:青岛生物能源与过程研究所

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