中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
首页 机构 成果 学者
  
  1. CAS IR Grid
  2. 上海硅酸盐研究所
  3. 中国科学院上海硅酸盐研究所
  4. 高性能陶瓷和超微结构国家重点实验室
  5. 期刊论文
Solar-Light-Driven Pure Water Splitting with Ultrathin BiOCl Nanosheets

文献类型：期刊论文

作者Zhang, Ling1; Han, Zhongkang2,3; Wang, Wenzhong1; Li, Xiaoman1; Su, Yang1; Jiang, Dong1; Lei, Xiaoling2,3; Sun, Songmei1
刊名CHEMISTRY-A EUROPEAN JOURNAL
出版日期2015-12-07
卷号21期号:50页码:18089-18094
关键词charge-carrier separation nanosheets photocatalysts solar energy water splitting
英文摘要A suitable photocatalyst for overall water splitting has been produced by overcoming the disadvantage of the band structure in bulk BiOCl by reducing the thickness to the quantum scale. The ultrathin BiOCl nanosheets with surface/subsurface defects realized the solar-driven pure water splitting in the absence of any co-catalysts or sacrificial agent. These surface defects cannot only shift both the valence band and conduction band upwards for band-gap narrowing but also promote charge-carrier separation. The amount of defects in the outer layer surface of BiOCl results in an enhancement of carrier density and faster charge transport. First-principles calculations provide clear evidence that the formation of surface oxygen vacancies is easier for the ultrathin BiOCl nanosheets than for its thicker counterpart. These defects can serve as active sites to effectively adsorb and dissociate H2O molecules, resulting in a significantly improved water-splitting performance.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]MOLECULAR-OXYGEN ACTIVATION ; PHOTOCATALYTIC ACTIVITY ; ELECTRONIC-STRUCTURE ; BISMUTH OXYCHLORIDE ; RECENT PROGRESS ; BLACK TIO2 ; HYDROGEN ; VACANCIES ; BIVO4 ; OXIDE
收录类别SCI
语种英语
WOS记录号WOS:000367186000016
源URL[http://ir.sic.ac.cn/handle/331005/8234]  
专题上海硅酸盐研究所_高性能陶瓷和超微结构国家重点实验室_期刊论文
作者单位1.Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Appl Phys, Div Interfacial Water, Shanghai 200050, Peoples R China
3.Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Shanghai 200050, Peoples R China
推荐引用方式
GB/T 7714		 Zhang, Ling,Han, Zhongkang,Wang, Wenzhong,et al. Solar-Light-Driven Pure Water Splitting with Ultrathin BiOCl Nanosheets[J]. CHEMISTRY-A EUROPEAN JOURNAL,2015,21(50):18089-18094.
APA Zhang, Ling.,Han, Zhongkang.,Wang, Wenzhong.,Li, Xiaoman.,Su, Yang.,...&Sun, Songmei.(2015).Solar-Light-Driven Pure Water Splitting with Ultrathin BiOCl Nanosheets.CHEMISTRY-A EUROPEAN JOURNAL,21(50),18089-18094.
MLA Zhang, Ling,et al."Solar-Light-Driven Pure Water Splitting with Ultrathin BiOCl Nanosheets".CHEMISTRY-A EUROPEAN JOURNAL 21.50(2015):18089-18094.

入库方式： OAI收割

来源：上海硅酸盐研究所

浏览0
下载0
收藏0
其他版本

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。