An Unprecedented Effective Enzymatic Carboxylation of Phenols
文献类型：期刊论文
| 作者 | Ren, Jie; Yao, Peiyuan; Yu, Shanshan; Dong, Wenyue; Chen, Qijia; Feng, Jinhui; Wu, Qiaqing; Zhu, Dunming1 |
| 刊名 | ACS CATALYSIS
 |
| 出版日期 | 2016-02-01 |
| 卷号 | 6期号:2页码:564-567 |
| 关键词 | enzymatic carboxylation reaction equilibrium quaternary ammonium salts carboxylase decarboxylase Kolbe-Schmitt reaction |
| 英文摘要 | It is well-known that the equilibrium of the enzymatic Kolbe-Schmitt reaction is unfavorable for the carboxylation direction. A new method was developed to push the reaction equilibrium toward the carboxylation of resorcinol and catechol by adding quaternary ammonium salts into the reaction system. The yields of the carboxylation products were increased up to 97% from less than 40%. The precipitation capacity of the quaternary ammonium salts of the carboxylic acid products is the driving force for the reaction equilibrium shift. Therefore, effective enzymatic carboxylation of phenols has been achieved for the first time. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | KOLBE-SCHMITT REACTION ; GAMMA-RESORCYLATE DECARBOXYLASE ; P-AMINOSALICYLIC ACID ; SP STRAIN MTP-10005 ; HYDROXYSTYRENE DERIVATIVES ; CRYSTAL-STRUCTURES ; IONIC LIQUIDS ; PURIFICATION ; SOLVENTS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000369774900008 |
| 源URL | [http://124.16.173.210/handle/834782/1536]  |
| 专题 | 天津工业生物技术研究所_生物催化与绿色化工 朱敦明_期刊论文 |
| 作者单位 | 1.Chinese Acad Sci, Tianjin Inst Ind Biotechnol, Natl Engn Lab Ind Enzymes, Tianjin Airport Econ Area, 32 Xi Qi Dao, Tianjin 300308, Tianjin, Peoples R China 2.Chinese Acad Sci, Tianjin Engn Res Ctr Biocatalyt Technol, Tianjin Inst Ind Biotechnol, Tianjin Airport Econ Area, 32 Xi Qi Dao, Tianjin 300308, Tianjin, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ren, Jie,Yao, Peiyuan,Yu, Shanshan,et al. An Unprecedented Effective Enzymatic Carboxylation of Phenols[J]. ACS CATALYSIS,2016,6(2):564-567. |
| APA | Ren, Jie.,Yao, Peiyuan.,Yu, Shanshan.,Dong, Wenyue.,Chen, Qijia.,...&Zhu, Dunming.(2016).An Unprecedented Effective Enzymatic Carboxylation of Phenols.ACS CATALYSIS,6(2),564-567. |
| MLA | Ren, Jie,et al."An Unprecedented Effective Enzymatic Carboxylation of Phenols".ACS CATALYSIS 6.2(2016):564-567. |
入库方式： OAI收割
来源：天津工业生物技术研究所
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