Fei-Phos ligand-controlled asymmetric palladium-catalyzed allylic substitutions with structurally diverse nucleophiles: scope and limitations
文献类型:期刊论文
作者 | Xu, Jian-Xing1; Ye, Fei1; Bai XF(柏惺峰)1,2; Zhang, Jin1; Xu, Zheng1; Zheng, Zhan-Jiang1; Xu LW(徐利文)1,2 |
刊名 | RSC Advances |
出版日期 | 2016 |
卷号 | 6期号:51页码:45495-45502 |
ISSN号 | 2046-2069 |
通讯作者 | 徐利文 |
英文摘要 | To shed light on the scope and limitations of palladium-catalyzed allylic alkylation in the presence of chiral trans-1,2-diaminocyclohexane-derived Fei-Phos as an effective phosphine ligand, the asymmetric palladium-catalysed alkylation of structurally diverse hard/soft nucleophiles, including allylic etherification of alcohols and the allylic alkylation of activated methylene compounds, indoles, and aromatic amines were investigated in this study; the corresponding products with various functional groups were achieved in good yield and with high enantioselectivity (up to 99% ee). |
学科主题 | 物理化学与绿色催化 |
资助信息 | the National Natural Science Foundation of China (No. 21173064;51303043;21472031;21503060);Zhejiang Provincial Natural Science Foundation of China (LR14B030001) |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000376120100063 |
源URL | [http://210.77.64.217/handle/362003/20100] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
作者单位 | 1.Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 311121, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, Jian-Xing,Ye, Fei,Bai XF,et al. Fei-Phos ligand-controlled asymmetric palladium-catalyzed allylic substitutions with structurally diverse nucleophiles: scope and limitations[J]. RSC Advances,2016,6(51):45495-45502. |
APA | Xu, Jian-Xing.,Ye, Fei.,Bai XF.,Zhang, Jin.,Xu, Zheng.,...&Xu LW.(2016).Fei-Phos ligand-controlled asymmetric palladium-catalyzed allylic substitutions with structurally diverse nucleophiles: scope and limitations.RSC Advances,6(51),45495-45502. |
MLA | Xu, Jian-Xing,et al."Fei-Phos ligand-controlled asymmetric palladium-catalyzed allylic substitutions with structurally diverse nucleophiles: scope and limitations".RSC Advances 6.51(2016):45495-45502. |
入库方式: OAI收割
来源:兰州化学物理研究所
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