Rhodium-Catalyzed Cyclocarbonylation of Ketimines via C-H Bond Activation
文献类型：期刊论文
| 作者 | Gao B(高宝)1,2; Liu, Song1,3; Lan, Yu3; Huang HM(黄汉民)1 ; Huang HM(黄汉民)
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| 刊名 | Organometallics
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| 出版日期 | 2016 |
| 卷号 | 35期号:10页码:1480-1487 |
| ISSN号 | 0276-7333 |
| 通讯作者 | Lan, Yu ; 黄汉民 |
| 英文摘要 | A novel rhodium-catalyzed oxidative cyclocarbonylation of ketimines via cleavage of two C–H bonds was established, which provided a direct and reliable method for the synthesis of a wide range of 3-methyleneisoindolin-1-ones with mostly moderate yields. Preliminary experimental mechanistic studies and DFT calculations revealed that this reaction proceeds via imine–enamine tautomerization, N–H cleavage, C–H bond activation, CO insertion, and reductive elimination. The mechanism studies further ruled out an isolated cyclometalated rhodium complex being involved in the present reaction, which was different from many other documented rhodium-catalyzed C–H cyclization reactions. |
| 学科主题 | 物理化学与绿色催化 |
| 资助信息 | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21222203;21133011) |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000376548400023 |
| 源URL | [http://210.77.64.217/handle/362003/20112]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 通讯作者 | Huang HM(黄汉民) |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400030, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao B,Liu, Song,Lan, Yu,et al. Rhodium-Catalyzed Cyclocarbonylation of Ketimines via C-H Bond Activation[J]. Organometallics,2016,35(10):1480-1487. |
| APA | Gao B,Liu, Song,Lan, Yu,Huang HM,&黄汉民.(2016).Rhodium-Catalyzed Cyclocarbonylation of Ketimines via C-H Bond Activation.Organometallics,35(10),1480-1487. |
| MLA | Gao B,et al."Rhodium-Catalyzed Cyclocarbonylation of Ketimines via C-H Bond Activation".Organometallics 35.10(2016):1480-1487. |
入库方式： OAI收割
来源：兰州化学物理研究所
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