Solvent-Free Selective Condensations Based on the Formation of the Olefinic (C = C) Bond Catalyzed by Organocatalyst
文献类型：期刊论文
| 作者 | Song HY(宋河远)1,2 ; Jin RH(靳荣华)1; Jin FX(金福祥)1; Kang MR(康美荣)1; Li Z(李臻)1; Chen J(陈静)1; Chen J(陈静); Li Z(李臻)
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| 刊名 | Catalysts
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| 出版日期 | 2016 |
| 卷号 | 6期号:7页码:106(1-8) |
| 关键词 | aldol condensation Knoevenagel condensation organocatalysis solvent-free condition ketone aldehyde |
| ISSN号 | 2073-4344 |
| 通讯作者 | 李臻 ; 陈静 |
| 英文摘要 | Pyrrolidine and its derivatives were used to catalyze aldol and Knoevenagel condensations for the formation of the olefinic (C = C) bond under solvent-free conditions. The 3-pyrrolidinamine showed high activity and afforded excellent yields of alpha, beta-unsaturated compounds. The aldol condensation of aromatic/heterocyclic aldehydes with ketones affords enones in high conversion (99.5%) and selectivity (92.7%). Good to excellent yields of alpha, beta-unsaturated compounds were obtained in the Knoevenagel condensation of aldehydes with methylene-activated substrates. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (Project No. 21473225) |
| 语种 | 英语 |
| WOS记录号 | WOS:000380771900015 |
| 源URL | [http://210.77.64.217/handle/362003/20224]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 通讯作者 | Chen J(陈静); Li Z(李臻) |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song HY,Jin RH,Jin FX,et al. Solvent-Free Selective Condensations Based on the Formation of the Olefinic (C = C) Bond Catalyzed by Organocatalyst[J]. Catalysts,2016,6(7):106(1-8). |
| APA | Song HY.,Jin RH.,Jin FX.,Kang MR.,Li Z.,...&李臻.(2016).Solvent-Free Selective Condensations Based on the Formation of the Olefinic (C = C) Bond Catalyzed by Organocatalyst.Catalysts,6(7),106(1-8). |
| MLA | Song HY,et al."Solvent-Free Selective Condensations Based on the Formation of the Olefinic (C = C) Bond Catalyzed by Organocatalyst".Catalysts 6.7(2016):106(1-8). |
入库方式： OAI收割
来源：兰州化学物理研究所
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