Efficient Benzylic and Aliphatic C-H Oxidation with Selectivity for Methylenic Sites Catalyzed by a Bioinspired Manganese Complex
文献类型：期刊论文
| 作者 | Shen DY(沈都益)1,2 ; Miao CX(苗成霞)1; Wang SF(王寿峰)1; Xia CG(夏春谷)1; Sun W(孙伟)1
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| 刊名 | Organic Letters
 |
| 出版日期 | 2014 |
| 卷号 | 16期号:4页码:1108-1111 |
| ISSN号 | 1523-7060 |
| 通讯作者 | 孙伟 |
| 英文摘要 | A benzimidazole-based nonheme manganese complex efficiently catalyzes benzylic, aliphatic C–H as well as tertiary C–H oxidation with hydrogen peroxide as the oxidant in the presence of acetic acid as additive. 18O labeling experiments suggest the reaction may proceed via a high-valent manganese-oxo intermediate. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (No. 21073210;21133011;21103206) |
| 语种 | 英语 |
| WOS记录号 | WOS:000331926800020 |
| 源URL | [http://210.77.64.217/handle/362003/20278]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shen DY,Miao CX,Wang SF,et al. Efficient Benzylic and Aliphatic C-H Oxidation with Selectivity for Methylenic Sites Catalyzed by a Bioinspired Manganese Complex[J]. Organic Letters,2014,16(4):1108-1111. |
| APA | Shen DY,Miao CX,Wang SF,Xia CG,&Sun W.(2014).Efficient Benzylic and Aliphatic C-H Oxidation with Selectivity for Methylenic Sites Catalyzed by a Bioinspired Manganese Complex.Organic Letters,16(4),1108-1111. |
| MLA | Shen DY,et al."Efficient Benzylic and Aliphatic C-H Oxidation with Selectivity for Methylenic Sites Catalyzed by a Bioinspired Manganese Complex".Organic Letters 16.4(2014):1108-1111. |
入库方式： OAI收割
来源：兰州化学物理研究所
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