Aerobic oxidation of secondary alcohols using NHPI and iron salt as catalysts at room temperature
文献类型：期刊论文
| 作者 | Zhao, Hanging1; Sun W(孙伟)2 ; Miao CX(苗成霞)2; Zhao, Quanyi1
|
| 刊名 | Journal of Molecular Catalysis A: Chemical
 |
| 出版日期 | 2014 |
| 卷号 | 393页码:62-67 |
| 关键词 | N-hydroxyphthalimide Secondary alcohols Aerobic oxidation Iron salts |
| ISSN号 | 1381-1169 |
| 通讯作者 | 苗成霞 ; Zhao, Quanyi |
| 英文摘要 | Aerobic oxidation of various alcohols has been accomplished by using a novel catalytic system, N-hydroxyphthalimide (NHPI) combined with Fe(NO3)3·9H2O. Secondary alcohols, especially benzylic and aliphatic alcohols, were smoothly transformed into corresponding ketones with up to 92% yields at room temperature under one atmosphere pressure of oxygen. The influences of reaction conditions such as solvent, different metal catalyst, catalyst loading and the structure of alcohols on the promotion effect were studied. And a possible radical mechanism for the oxidation of secondary alcohols in Fe(NO3)3·9H2O/NHPI/O2 system was proposed. |
| 学科主题 | 物理化学与绿色催化 |
| 收录类别 | SCI |
| 资助信息 | the National Natural Science Foundation of China (21103207;21133011) |
| 语种 | 英语 |
| WOS记录号 | WOS:000341462700008 |
| 源URL | [http://210.77.64.217/handle/362003/20317]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 作者单位 | 1.Lanzhou Univ, Sch Pharm, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Hanging,Sun W,Miao CX,et al. Aerobic oxidation of secondary alcohols using NHPI and iron salt as catalysts at room temperature[J]. Journal of Molecular Catalysis A: Chemical,2014,393:62-67. |
| APA | Zhao, Hanging,Sun W,Miao CX,&Zhao, Quanyi.(2014).Aerobic oxidation of secondary alcohols using NHPI and iron salt as catalysts at room temperature.Journal of Molecular Catalysis A: Chemical,393,62-67. |
| MLA | Zhao, Hanging,et al."Aerobic oxidation of secondary alcohols using NHPI and iron salt as catalysts at room temperature".Journal of Molecular Catalysis A: Chemical 393(2014):62-67. |
入库方式： OAI收割
来源：兰州化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。