中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Size effect of gold nanoparticles on the electrocatalytic oxidation of carbon monoxide in alkaline solution

文献类型:期刊论文

作者Geng DS(耿东生)1,2; Lu GX(吕功煊)1
刊名Journal of Nanoparticle Research
出版日期2007
卷号9期号:6页码:1145-1151
关键词size effect nanoparticles electrocatalytic electro-oxidation catalyst colloids
ISSN号1388-0764
通讯作者吕功煊
英文摘要

This paper describes preliminary findings of Au nanoparticle on glassy carbon (GC) electrodes for electro-oxidation of carbon monoxide in basic conditions. Electrochemical cyclic voltammetric results showed that CO oxidation simultaneously occurred in the anodic and cathodic sweeps during one cycle, and CO electro-oxidation activity was remarkably different in the anode for the different sized Au nanoparticles. The ultrafine catalyst metal particles (2 and 6 nm Au) were more active compared to the larger ones (12, 24 and 41 nm Au). The dependence of the activity on the particle size can be explained in terms of their effect on the number of active sites and the different surface gold oxide species.

学科主题物理化学与绿色催化
收录类别SCI
资助信息The 973 (G20000264) Research Fund
语种英语
源URL[http://210.77.64.217/handle/362003/20560]  
专题兰州化学物理研究所_OSSO国家重点实验室
作者单位1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou 730000, China
2.Graduate University of Chinese Academy of Sciences Beijing P.R. China
推荐引用方式
GB/T 7714
Geng DS,Lu GX. Size effect of gold nanoparticles on the electrocatalytic oxidation of carbon monoxide in alkaline solution[J]. Journal of Nanoparticle Research,2007,9(6):1145-1151.
APA Geng DS,&Lu GX.(2007).Size effect of gold nanoparticles on the electrocatalytic oxidation of carbon monoxide in alkaline solution.Journal of Nanoparticle Research,9(6),1145-1151.
MLA Geng DS,et al."Size effect of gold nanoparticles on the electrocatalytic oxidation of carbon monoxide in alkaline solution".Journal of Nanoparticle Research 9.6(2007):1145-1151.

入库方式: OAI收割

来源:兰州化学物理研究所

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