Size effect of gold nanoparticles on the electrocatalytic oxidation of carbon monoxide in alkaline solution
文献类型:期刊论文
作者 | Geng DS(耿东生)1,2; Lu GX(吕功煊)1![]() |
刊名 | Journal of Nanoparticle Research
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出版日期 | 2007 |
卷号 | 9期号:6页码:1145-1151 |
关键词 | size effect nanoparticles electrocatalytic electro-oxidation catalyst colloids |
ISSN号 | 1388-0764 |
通讯作者 | 吕功煊 |
英文摘要 | This paper describes preliminary findings of Au nanoparticle on glassy carbon (GC) electrodes for electro-oxidation of carbon monoxide in basic conditions. Electrochemical cyclic voltammetric results showed that CO oxidation simultaneously occurred in the anodic and cathodic sweeps during one cycle, and CO electro-oxidation activity was remarkably different in the anode for the different sized Au nanoparticles. The ultrafine catalyst metal particles (2 and 6 nm Au) were more active compared to the larger ones (12, 24 and 41 nm Au). The dependence of the activity on the particle size can be explained in terms of their effect on the number of active sites and the different surface gold oxide species. |
学科主题 | 物理化学与绿色催化 |
收录类别 | SCI |
资助信息 | The 973 (G20000264) Research Fund |
语种 | 英语 |
源URL | [http://210.77.64.217/handle/362003/20560] ![]() |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
作者单位 | 1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou 730000, China 2.Graduate University of Chinese Academy of Sciences Beijing P.R. China |
推荐引用方式 GB/T 7714 | Geng DS,Lu GX. Size effect of gold nanoparticles on the electrocatalytic oxidation of carbon monoxide in alkaline solution[J]. Journal of Nanoparticle Research,2007,9(6):1145-1151. |
APA | Geng DS,&Lu GX.(2007).Size effect of gold nanoparticles on the electrocatalytic oxidation of carbon monoxide in alkaline solution.Journal of Nanoparticle Research,9(6),1145-1151. |
MLA | Geng DS,et al."Size effect of gold nanoparticles on the electrocatalytic oxidation of carbon monoxide in alkaline solution".Journal of Nanoparticle Research 9.6(2007):1145-1151. |
入库方式: OAI收割
来源:兰州化学物理研究所
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