A mechanistic study on multifunctional Fei-Phos ligand-controlled asymmetric palladium-catalyzed allylic substitutions
文献类型:期刊论文
作者 | Xu, Jian-Xing1; Ye, Fei1; Bai XF(柏惺峰)1,2; Cui, Yu-Ming1; Xu, Zheng1; Zheng ZJ(郑战江)1; Xu LW(徐利文)1,2 |
刊名 | RSC Advances |
出版日期 | 2016 |
卷号 | 6期号:74页码:70624-70631 |
ISSN号 | 2046-2069 |
通讯作者 | 徐利文 |
英文摘要 | To shield light on the mechanism of palladium-catalyzed allylic substitutions with structurally diverse nucleophiles (up to 99% ee) in the presence of Fei-Phos ligand (chiral trans-1,2-diaminocyclohexane-derived biphosphine, CycloN2P2-Phos) as an effective chiral P-ligand, mechanistic studies were performed for clarification of the role of multifunctional Fei-Phos in this reaction. The cooperative action of nitrogen and phosphorous atoms in the present Pd-catalyzed allylic alkylation is proved to be a diphosphine-based catalyst system but not a nitrogen-controlled or monophosphine-involved transition state. |
学科主题 | 物理化学与绿色催化 |
资助信息 | the National Natural Science Foundation of China (No. 21173064;51303043;21472031;21503060);Zhejiang Provincial Natural Science Foundation of China (LR14B030001) |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000381512800114 |
源URL | [http://210.77.64.217/handle/362003/20683] |
专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
作者单位 | 1.Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 311121, Zhejiang, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, Jian-Xing,Ye, Fei,Bai XF,et al. A mechanistic study on multifunctional Fei-Phos ligand-controlled asymmetric palladium-catalyzed allylic substitutions[J]. RSC Advances,2016,6(74):70624-70631. |
APA | Xu, Jian-Xing.,Ye, Fei.,Bai XF.,Cui, Yu-Ming.,Xu, Zheng.,...&Xu LW.(2016).A mechanistic study on multifunctional Fei-Phos ligand-controlled asymmetric palladium-catalyzed allylic substitutions.RSC Advances,6(74),70624-70631. |
MLA | Xu, Jian-Xing,et al."A mechanistic study on multifunctional Fei-Phos ligand-controlled asymmetric palladium-catalyzed allylic substitutions".RSC Advances 6.74(2016):70624-70631. |
入库方式: OAI收割
来源:兰州化学物理研究所
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