中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
首页 机构 成果 学者
  
  1. CAS IR Grid
  2. 兰州化学物理研究所
  3. 中国科学院兰州化学物理研究所
  4. OSSO国家重点实验室
An Aluminum Triflate-Catalyzed Intramolecular Reaction Sequence Toward Concise Construction of the Tetrahydropyrido[1,2-a]indol-6-one Skeleton

文献类型：期刊论文

作者Wang, Jun-Jiao1; Zhou, An-Xi1; Wang, Gang-Wei1; Yang SD(杨尚东)1,2
刊名Advanced Synthesis and Catalysis
出版日期2014
卷号356期号:16页码:3356-3362
关键词N-acyliminium ions aluminum triflate dearomatization Mannich-like cyclization
ISSN号1615-4150
通讯作者杨尚东
英文摘要

An aluminum triflate-catalyzed intramolecular reaction sequence involving protonation and Mannich-like nucleophilic addition of indoles toward the concise construction of the tetrahydropyrido[1,2-a]indol-6-one skeleton is reported. This new reaction pattern employs a carbon atom as nucleophile to form a C[BOND]C bond which bears one or even two quaternary carbons and leads to the dearomatization of indoles with high atom economy.

学科主题物理化学与绿色催化
收录类别SCI
资助信息the NSFC (No. 21272100);Program for Changjiang Scholars and Innovative Research Team in University (PCSIRT: IRT1138);Program for New Century Excellent Talents in University (NCET-11-0215;lzujbky-2013-k07)
语种英语
WOS记录号WOS:000344546600013
源URL[http://210.77.64.217/handle/362003/20707]  
专题兰州化学物理研究所_OSSO国家重点实验室
作者单位1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714		 Wang, Jun-Jiao,Zhou, An-Xi,Wang, Gang-Wei,et al. An Aluminum Triflate-Catalyzed Intramolecular Reaction Sequence Toward Concise Construction of the Tetrahydropyrido[1,2-a]indol-6-one Skeleton[J]. Advanced Synthesis and Catalysis,2014,356(16):3356-3362.
APA Wang, Jun-Jiao,Zhou, An-Xi,Wang, Gang-Wei,&Yang SD.(2014).An Aluminum Triflate-Catalyzed Intramolecular Reaction Sequence Toward Concise Construction of the Tetrahydropyrido[1,2-a]indol-6-one Skeleton.Advanced Synthesis and Catalysis,356(16),3356-3362.
MLA Wang, Jun-Jiao,et al."An Aluminum Triflate-Catalyzed Intramolecular Reaction Sequence Toward Concise Construction of the Tetrahydropyrido[1,2-a]indol-6-one Skeleton".Advanced Synthesis and Catalysis 356.16(2014):3356-3362.

入库方式： OAI收割

来源：兰州化学物理研究所

浏览0
下载0
收藏0
其他版本

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。