Ti₃SiC₂/Cu composites with different contents of Cu were fabricated by mechanical alloying and spark plasma sintering method. The phase composition and structure of the composites were analyzed by X-ray diffractometry and scanning electron microscopy equipped with energy dispersive spectroscopy. The mechanical and tribological properties of Ti₃SiC₂/Cu composites were tested and analyzed compared with monolithic Ti₃SiC₂ in details. The results show that the Cu leads to the decomposition of Ti₃SiC₂ to produce TiC_x, Ti₅Si₃C_y, Cu₃Si, and TiSi₂C_z. The friction coefficient and wear rate of the composites are lower than that of monolithic Ti₃SiC₂, which is ascribed to the fixing effect of hard TiC_x, Ti₅Si₃C_y, and Cu₃Si to inhibit the abrasive friction and wear. However, at elevated temperatures (ranging from room temperature to 600 °C) the friction and wear of the composites are higher than those at room temperature. Plastic flowing and tribo-oxidation wear accompanied by material transference contribute to the increased friction and wear at elevated temperatures.