Palladium-Catalyzed/Norbornene-Mediated C-H Activation/N-Tosylhydrazone Insertion Reaction: A Route to Highly Functionalized Vinylarenes
文献类型:期刊论文
作者 | Zhou, Ping-Xin1; Zheng, Lan1; Ma, Jun-Wei1; Ye, Yu-Ying1; Liu XY(刘雪原)1; Xu PF(许鹏飞)1; Liang YM(梁永民)1,2 |
刊名 | Chemistry - A European Journal |
出版日期 | 2014 |
卷号 | 20期号:22页码:6745-6751 |
ISSN号 | 0947-6539 |
关键词 | CH activation CC coupling diazo compounds palladium synthetic methods |
通讯作者 | 许鹏飞 ; 梁永民 |
英文摘要 | A straightforward method for the synthesis of highly functionalized vinylarenes through palladium-catalyzed, norbornene-mediated CH activation/carbene migratory insertion is described. Extension to a one-pot procedure is also developed. Furthermore, this method can also be used to generate polysubstituted bicyclic molecules. The reaction proceeds under mild conditions to give the products in satisfactory yields using readily available starting materials. This is a Catellani–Lautens reaction that incorporates different types of coupling partners. Additionally, this reaction is the first to demonstrate the possibility of combining Pd-catalyzed insertion of diazo compounds and Pd-catalyzed CH activation. |
学科主题 | 材料科学与物理化学 |
资助信息 | the National Science Foundation (NSF 21072080;21272101);the National Basic Research Program of China (973 Program) 2010CB833203;the “111” program of MOE;PCSIRT: IRT1138 |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000336002200027 |
源URL | [http://210.77.64.217/handle/362003/20292] |
专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
作者单位 | 1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Zhou, Ping-Xin,Zheng, Lan,Ma, Jun-Wei,et al. Palladium-Catalyzed/Norbornene-Mediated C-H Activation/N-Tosylhydrazone Insertion Reaction: A Route to Highly Functionalized Vinylarenes[J]. Chemistry - A European Journal,2014,20(22):6745-6751. |
APA | Zhou, Ping-Xin.,Zheng, Lan.,Ma, Jun-Wei.,Ye, Yu-Ying.,Liu XY.,...&Liang YM.(2014).Palladium-Catalyzed/Norbornene-Mediated C-H Activation/N-Tosylhydrazone Insertion Reaction: A Route to Highly Functionalized Vinylarenes.Chemistry - A European Journal,20(22),6745-6751. |
MLA | Zhou, Ping-Xin,et al."Palladium-Catalyzed/Norbornene-Mediated C-H Activation/N-Tosylhydrazone Insertion Reaction: A Route to Highly Functionalized Vinylarenes".Chemistry - A European Journal 20.22(2014):6745-6751. |
入库方式: OAI收割
来源:兰州化学物理研究所
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。