Electrochemical determination of arsenic(III) with ultra-high anti-interference performance using Au-Cu bimetallic nanoparticles
文献类型：期刊论文
| 作者 | Yang, M; Guo, Z; Li, LN; Huang, YY; Liu, JH; Zhou, Q; Chen, X; Huang, XJ |
| 刊名 | SENSORS AND ACTUATORS B-CHEMICAL
 |
| 出版日期 | 2016 |
| 卷号 | 231期号:-页码:70—78 |
| 关键词 | GLASSY-CARBON ELECTRODES CATHODIC STRIPPING VOLTAMMETRY GOLD-COPPER NANOPARTICLES ONE-STEP SYNTHESIS ALLOY NANOPARTICLES SELECTIVE DETECTION FACILE SYNTHESIS TRACE AMOUNTS FORMIC-ACID OXIDATION |
| ISSN号 | 0925-4005 |
| 通讯作者 | Chen, X ; Huang, XJ (reprint author), Chinese Acad Sci, Inst Intelligent Machines, Hefei 230031, Peoples R China. |
| 英文摘要 | Bimetallic nanoparticles provide a new opportunity for enhancing electrocatalytic activity because of some possible synergetic effects. In this study, different compositions of Au-Cu bimetallic nanoparticles are prepared via a simple hydrothermal method. The structure of Au-Cu bimetallic nanoparticles is characterized by using X-ray absorption fine structure (XAFS) techniques, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The correlations between electrochemical performance and the compositions of Au-Cu bimetallic nanoparticles on the determination of arsenic(III) are investigated through square wave anodic stripping voltammetry (SWASV). It is found that the amount of copper (Cu) in Au-Cu bimetallic nanoparticles is critical to the detection of arsenic(III). The XAFS results indicated that the Au-Au bond length (RAu-Au) can be influenced by the Cu concentration in the materials. Different RAu-Au of Au-Cu nanoparticles lead to the different electrochemical catalytic activity toward arsenic(III), further revealing the different electrochemical behavior. Compared with Au nanoparticles and commercial Au electrode, the Au-Cu bimetallic nanoparticles showed enhanced electrochemical performance with high sensitivity at ppb level, low detection limit. Moreover, the Au89Cu11 bimetallic nanoparticles exhibited ultra-high anti-interference performance on the detection of arsenic(III). (C) 2016 Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000374330900009 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/25707]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Yang, M,Guo, Z,Li, LN,et al. Electrochemical determination of arsenic(III) with ultra-high anti-interference performance using Au-Cu bimetallic nanoparticles[J]. SENSORS AND ACTUATORS B-CHEMICAL,2016,231(-):70—78. |
| APA | Yang, M.,Guo, Z.,Li, LN.,Huang, YY.,Liu, JH.,...&Huang, XJ.(2016).Electrochemical determination of arsenic(III) with ultra-high anti-interference performance using Au-Cu bimetallic nanoparticles.SENSORS AND ACTUATORS B-CHEMICAL,231(-),70—78. |
| MLA | Yang, M,et al."Electrochemical determination of arsenic(III) with ultra-high anti-interference performance using Au-Cu bimetallic nanoparticles".SENSORS AND ACTUATORS B-CHEMICAL 231.-(2016):70—78. |
入库方式： OAI收割
来源：上海应用物理研究所
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