Enhanced Aerogen- Interaction by a Cation- Force
文献类型：期刊论文
| 作者 | Miao, JJ; Song, B; Gao, Y |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2016 |
| 卷号 | 22期号:8页码:2586—2589 |
| 关键词 | PI INTERACTIONS AROMATIC RINGS NONCOVALENT INTERACTIONS BIOLOGICAL RECOGNITION COMPLIANCE CONSTANTS PERTURBATION-THEORY XENON INHIBITION COMPLEXES STRENGTHS |
| ISSN号 | 0947-6539 |
| 通讯作者 | Gao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Div Interfacial Water, Shanghai 201800, Peoples R China. ; Gao, Y (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Key Lab Interfacial Phys & Technol, Shanghai 201800, Peoples R China. |
| 英文摘要 | The interaction between a noble gas atom and an aromatic -electron system, which mainly originates from the London dispersion force, is very weak and has not attracted enough attention yet. Herein, we reported a type of notably enhanced aerogen- interaction between cation-systems and noble gas atoms. The binding strength of a divalent cation-system with a xenon atom is comparable to a moderate hydrogen bond (up to ca.7 kcalmol(-1)), whereas krypton and argon atoms produce slightly weaker interactions. Energy-decomposition analysis reveals that the induction interaction is responsible for the stabilization of divalent cation-Xe species besides the dispersion interaction. Our results might be helpful to increase the understanding of some unsolved mysteries of aerogens. |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000370193000004 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/25713]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Miao, JJ,Song, B,Gao, Y. Enhanced Aerogen- Interaction by a Cation- Force[J]. CHEMISTRY-A EUROPEAN JOURNAL,2016,22(8):2586—2589. |
| APA | Miao, JJ,Song, B,&Gao, Y.(2016).Enhanced Aerogen- Interaction by a Cation- Force.CHEMISTRY-A EUROPEAN JOURNAL,22(8),2586—2589. |
| MLA | Miao, JJ,et al."Enhanced Aerogen- Interaction by a Cation- Force".CHEMISTRY-A EUROPEAN JOURNAL 22.8(2016):2586—2589. |
入库方式： OAI收割
来源：上海应用物理研究所
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