Efficient valorization of biomass to biofuels with bifunctional solid catalytic materials
文献类型：期刊论文
| 作者 | Li, Hu ; Fang, Zhen ; Smith, Richard L., Jr. ; Yang, Song |
| 刊名 | PROGRESS IN ENERGY AND COMBUSTION SCIENCE
 |
| 出版日期 | 2016 |
| 卷号 | 55期号:x页码:98-194 |
| 关键词 | Lignocellulose Catalyst design Catalysis One-pot reaction Platform chemicals Nanotechnology |
| 中文摘要 | Mono-functional catalytic materials are used for many types of chemical transformations, but are tedious for delivering products from multiple-step reactions required for the valorization of biomass. An emerging trend is to integrate catalytic transformations, reaction engineering and product separation into a single operation, wherein catalyst design is considered as the key approach to develop efficient, low energy and environmentally-friendly reaction systems. Bifunctional solid catalysts open a door for carrying out domino/cascade- and tandem/sequential-type reactions in a single pot, for which the number of isolation or purification steps can be lessened or eliminated so that removal of unwanted by-products becomes unnecessary. This review introduces bifunctional materials used in one-pot multiple transformations of biomass into biofuels and related chemicals. Emphasis is placed on the assessment of the bifunctionality of catalytic materials, including Bronsted-Lewis acid, acid -base, and metal particles-acid or base bifunctional catalysts with some discussion being on combined catalytic systems with electrochemical, chemoenzymatic and photochemical methods. Plausible reaction mechanisms for key pathways are shown. Relevant auxiliaries to boost catalytic activity and product selectivity, such as reaction media, heating modes and morphological properties of the catalytic materials are analyzed. Use of appropriate bifunctional catalytic materials provides many opportunities for design of highly efficient reaction systems and simplified processing for producing biofuels and chemicals from lignocellulosic biomass. |
| 公开日期 | 2016-07-25 |
| 源URL | [http://ir.xtbg.org.cn/handle/353005/9982]  |
| 专题 | 西双版纳热带植物园_生物能源研究组 |
| 推荐引用方式 GB/T 7714 | Li, Hu,Fang, Zhen,Smith, Richard L., Jr.,et al. Efficient valorization of biomass to biofuels with bifunctional solid catalytic materials[J]. PROGRESS IN ENERGY AND COMBUSTION SCIENCE,2016,55(x):98-194. |
| APA | Li, Hu,Fang, Zhen,Smith, Richard L., Jr.,&Yang, Song.(2016).Efficient valorization of biomass to biofuels with bifunctional solid catalytic materials.PROGRESS IN ENERGY AND COMBUSTION SCIENCE,55(x),98-194. |
| MLA | Li, Hu,et al."Efficient valorization of biomass to biofuels with bifunctional solid catalytic materials".PROGRESS IN ENERGY AND COMBUSTION SCIENCE 55.x(2016):98-194. |
入库方式： OAI收割
来源：西双版纳热带植物园
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。