Superbase/saccharide: An ecologically benign catalyst for efficient fixation of CO2 into cyclic carbonates
文献类型：期刊论文
| 作者 | Cheng, Weiguo; Xu, Fei; Sun, Jian; Dong, Kun; Ma, Congkai; Zhang, Suojiang |
| 刊名 | SYNTHETIC COMMUNICATIONS
 |
| 出版日期 | 2016 |
| 卷号 | 46期号:6页码:497-508 |
| 关键词 | Carbon dioxide cycloaddition epoxide saccharide superbase |
| ISSN号 | 0039-7911 |
| 英文摘要 | An ecologically benign catalytic system consisting of superbase and saccharide was developed for CO2 chemical fixation with epoxides under metal-free and halide-free conditions. Because of the synergistic effect played by superbase and saccharide on the activations of CO2 and epoxide, the reaction could be performed with good activity and selectivity. A possible catalytic mechanism of the hydrogen-bonding of saccharide and activation of the carbon atom by 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) was proposed. The process is a simple, biocompatible, and ecological route for CO2 chemical fixation into high-value chemicals. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Organic |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | FUNCTIONALIZED IONIC LIQUID ; CHEMICAL FIXATION ; HETEROGENEOUS CATALYST ; ORGANIC CARBONATES ; PROPYLENE-OXIDE ; BASICITY SCALE ; HYDROGEN-BOND ; DIOXIDE ; EPOXIDES ; CYCLOADDITION |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000374249000002 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/21005]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cheng, Weiguo,Xu, Fei,Sun, Jian,et al. Superbase/saccharide: An ecologically benign catalyst for efficient fixation of CO2 into cyclic carbonates[J]. SYNTHETIC COMMUNICATIONS,2016,46(6):497-508. |
| APA | Cheng, Weiguo,Xu, Fei,Sun, Jian,Dong, Kun,Ma, Congkai,&Zhang, Suojiang.(2016).Superbase/saccharide: An ecologically benign catalyst for efficient fixation of CO2 into cyclic carbonates.SYNTHETIC COMMUNICATIONS,46(6),497-508. |
| MLA | Cheng, Weiguo,et al."Superbase/saccharide: An ecologically benign catalyst for efficient fixation of CO2 into cyclic carbonates".SYNTHETIC COMMUNICATIONS 46.6(2016):497-508. |
入库方式： OAI收割
来源：过程工程研究所
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