Cobalt-Catalyzed Dehydrogenative Coupling of Alcohols/Aldehydes and Amines: An Important Role for Imine Hydration
文献类型：期刊论文
| 作者 | Guo, Ya-Fei1,2; Ren, Tian-Lu1; Xu, Bao-Hua1; Wang, Yao-Feng1; Zhang, Suo-Jiang1 |
| 刊名 | ASIAN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2016-04-01 |
| 卷号 | 5期号:4页码:568-574 |
| 关键词 | cobalt cooperative catalysis iodides iminehydration oxidative amidation |
| ISSN号 | 2193-5807 |
| 英文摘要 | A cobalt and iodide co-catalyzed oxidative amidation reaction between alcohols or aldehydes and amines has been developed. The reactions proceeded smoothly under mild conditions using tert-butyl hydroperoxide solution in water as the terminal oxidant, with broad functional group tolerance. Mechanistic studies indicated that the tBuO/tBuOO radical generated insitu is the active species responsible for hydrogen abstraction in this catalytic process, and not IO-/IO2-/IO3- ions. Investigation into the reaction mechanism also revealed the potential transiency of a hemiaminal and the important role of its regeneration by imine hydration. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Organic |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | AMIDE BOND FORMATION ; INTRAMOLECULAR SCHMIDT REACTIONS ; DIRECT OXIDATIVE AMIDATION ; N-HYDROXYSUCCINIMIDE ; HYDROCHLORIDE SALTS ; TERTIARY-AMINES ; BENZYL ALCOHOLS ; ALDEHYDES ; MILD ; REARRANGEMENT |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000374772300018 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/21025]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc,Key Lab Gr, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guo, Ya-Fei,Ren, Tian-Lu,Xu, Bao-Hua,et al. Cobalt-Catalyzed Dehydrogenative Coupling of Alcohols/Aldehydes and Amines: An Important Role for Imine Hydration[J]. ASIAN JOURNAL OF ORGANIC CHEMISTRY,2016,5(4):568-574. |
| APA | Guo, Ya-Fei,Ren, Tian-Lu,Xu, Bao-Hua,Wang, Yao-Feng,&Zhang, Suo-Jiang.(2016).Cobalt-Catalyzed Dehydrogenative Coupling of Alcohols/Aldehydes and Amines: An Important Role for Imine Hydration.ASIAN JOURNAL OF ORGANIC CHEMISTRY,5(4),568-574. |
| MLA | Guo, Ya-Fei,et al."Cobalt-Catalyzed Dehydrogenative Coupling of Alcohols/Aldehydes and Amines: An Important Role for Imine Hydration".ASIAN JOURNAL OF ORGANIC CHEMISTRY 5.4(2016):568-574. |
入库方式： OAI收割
来源：过程工程研究所
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