Microporous organic polymer-based lithium ion batteries with improved rate performance and energy density
文献类型：期刊论文
| 作者 | Zhang, Chong1,2; Yang, Xiao1; Ren, Wenfeng2; Wang, Yanhong2; Su, Fabing2; Jiang, Jia-Xing1 |
| 刊名 | JOURNAL OF POWER SOURCES
 |
| 出版日期 | 2016-06-15 |
| 卷号 | 317期号:JUNE页码:49-56 |
| 关键词 | Triphenylamine Microporous organic polymers Organic cathode materials Electrochemical characteristics Lithium ion batteries |
| ISSN号 | 0378-7753 |
| 英文摘要 | Microporous organic polymers with triphenylamine segments were employed as cathode materials for lithium ion batteries. YPTPA with the highest surface area exhibits a discharge plateau at similar to 3.6 V vs. Li/Li+, an initial Coulombic efficiency of 96.8% at 50 mA g(-1) and a discharge capacity of 105.7 mAh g(-1) at 200 mA g(-1). Compared to the homo-coupled polymer of OPTPA with relatively low surface area (66 m(2) g(-1)), SPTPA and YPTPA with higher surface area (544 and 1557 m(2) g(-1), respectively) show enhanced rate performances and energy densities. YPTPA can deliver 97.6 mAh g(-1) within less than 3 min at high rate of 2000 mA g(-1) and the energy density of 334 Wh kg(-1) under an ultrahigh power density of 6816 W kg(-1), while OPTPA only presents 48.2 mAh g(-1) at 2000 mA g(-1) with an energy density of 155 Wh kg(-1) under 6414 W kg(-1). The great improvement in electrochemical properties of SPTPA and YPTPA demonstrates that increasing surface area of polymer cathodes by interweaving the redox-active units into microporous polymer skeleton is an efficient way to develop advanced polymer cathode materials with outstanding electrochemical performance. (C) 2016 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
| 类目[WOS] | Chemistry, Physical ; Electrochemistry ; Energy & Fuels ; Materials Science, Multidisciplinary |
| 研究领域[WOS] | Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science |
| 关键词[WOS] | GAS-ADSORPTION PROPERTIES ; HIGH-CAPACITY ; HIGH-POWER ; CATHODE MATERIALS ; SOLID-STATE ; STORAGE ; ELECTRODES ; CHARGE ; TRIPHENYLAMINE ; POLYTRIPHENYLAMINE |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000375823400007 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/21061]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.Shaanxi Normal Univ, Sch Mat Sci & Engn, Key Lab Macromol Sci Shaanxi Prov, Xian 710062, Shaanxi, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Chong,Yang, Xiao,Ren, Wenfeng,et al. Microporous organic polymer-based lithium ion batteries with improved rate performance and energy density[J]. JOURNAL OF POWER SOURCES,2016,317(JUNE):49-56. |
| APA | Zhang, Chong,Yang, Xiao,Ren, Wenfeng,Wang, Yanhong,Su, Fabing,&Jiang, Jia-Xing.(2016).Microporous organic polymer-based lithium ion batteries with improved rate performance and energy density.JOURNAL OF POWER SOURCES,317(JUNE),49-56. |
| MLA | Zhang, Chong,et al."Microporous organic polymer-based lithium ion batteries with improved rate performance and energy density".JOURNAL OF POWER SOURCES 317.JUNE(2016):49-56. |
入库方式： OAI收割
来源：过程工程研究所
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