Understanding the hydrogen bonds in ionic liquids and their roles in properties and reactions
文献类型：期刊论文
| 作者 | Dong, Kun1; Zhang, Suojiang1; Wang, Jianji2 |
| 刊名 | CHEMICAL COMMUNICATIONS
 |
| 出版日期 | 2016 |
| 卷号 | 52期号:41页码:6744-6764 |
| ISSN号 | 1359-7345 |
| 英文摘要 | Ionic liquids (ILs) have many potential applications in the chemical industry. In order to understand ILs, their molecular details have been extensively investigated. Intuitively, electrostatic forces are solely important in ILs. However, experiments and calculations have provided strong evidence for the existence of H-bonds in ILs and their roles in the properties and applications of ILs. As a structure-directing force, H-bonds are responsible for ionic pairing, stacking and self-assembling. Their geometric structure, interaction energy and electronic configuration in the ion-pairs of imidazolium-based ILs and protic ionic liquids (PILs) show a great number of differences compared to conventional H-bonds. In particular, their cooperation with electrostatic, dispersion and pi interactions embodies the physical nature of H-bonds in ILs, which anomalously influences their properties, leading to a decrease in their melting points and viscosities and thus fluidizing them. Using ILs as catalysts and solvents, many reactions can be activated by the presence of H-bonds, which reduce the reaction barriers and stabilize the transition states. In the dissolution of lignocellulosic biomass by ILs, H-bonds exhibit a most important role in disrupting the H-bonding network of cellulose and controlling microscopic ordering into domains. In this article, a critical review is presented regarding the structural features of H-bonds in ILs and PILs, the correlation between H-bonds and the properties of ILs, and the roles of H-bonds in typical reactions. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | MOLECULAR-DYNAMICS SIMULATIONS ; FAR-INFRARED SPECTROSCOPY ; CATION-ANION INTERACTION ; X-RAY-DIFFRACTION ; DENSITY-FUNCTIONAL THEORY ; ROOM-TEMPERATURE ; ETHYLAMMONIUM NITRATE ; BIOMASS RECALCITRANCE ; ELECTRONIC-STRUCTURE ; INTERACTION ENERGIES |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000376089000001 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/21085]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Henan Normal Univ, Sch Chem & Chem Engn, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Minist Educ,Key Lab Green Chem Media & React, Xinxiang 453007, Henan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dong, Kun,Zhang, Suojiang,Wang, Jianji. Understanding the hydrogen bonds in ionic liquids and their roles in properties and reactions[J]. CHEMICAL COMMUNICATIONS,2016,52(41):6744-6764. |
| APA | Dong, Kun,Zhang, Suojiang,&Wang, Jianji.(2016).Understanding the hydrogen bonds in ionic liquids and their roles in properties and reactions.CHEMICAL COMMUNICATIONS,52(41),6744-6764. |
| MLA | Dong, Kun,et al."Understanding the hydrogen bonds in ionic liquids and their roles in properties and reactions".CHEMICAL COMMUNICATIONS 52.41(2016):6744-6764. |
入库方式： OAI收割
来源：过程工程研究所
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