Efficient Dehydration of Fructose to 5-Hydroxymethylfurfural Catalyzed by Heteropolyacid Salts
文献类型：期刊论文
| 作者 | Song, Yanlei1; Wang, Xincheng1; Qu, Yongshui2; Huang, Chongpin1; Li, Yingxia1; Chen, Biaohua1 |
| 刊名 | CATALYSTS
 |
| 出版日期 | 2016-04-01 |
| 卷号 | 6期号:4页码:1 |
| 关键词 | 5-hydroxymethylfurfural dehydration fructose heteropolyacid salt response-surface-methodology optimisation |
| ISSN号 | 2073-4344 |
| 英文摘要 | 5-Hydroxymethylfurfural (5-HMF), which is derived from numerous industrial biomass resources, has attracted attention in recent years due to its potential as a building block. In this paper, a range of heteropolyacid salts had been investigated for the dehydration of fructose to 5-HMF. CePW12O40 demonstrated the best catalytic activity. Effects of fructose concentration, reaction temperature and reaction time on 5-HMF yield were investigated and optimised through a central composite design and response surface methodology. The optimal 5-HMF yield was 99.40% under the optimized reaction conditions of 5.48 mg/mL fructose loading, 158 degrees C temperature and 164 min reaction time. A kinetic analysis of the fructose conversion was also performed, and the activation energy and pre-exponential factor were obtained. |
| WOS标题词 | Science & Technology ; Physical Sciences |
| 类目[WOS] | Chemistry, Physical |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | HOT-COMPRESSED WATER ; IONIC LIQUID ; BIO-OIL ; CONVERSION ; GLUCOSE ; BIOMASS ; CHEMICALS ; 5-HYDROXYMETHYL-2-FURALDEHYDE ; TRANSFORMATION ; OPTIMIZATION |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000375210900001 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/21030]  |
| 专题 | 过程工程研究所_生化工程国家重点实验室 |
| 作者单位 | 1.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Natl Key Lab Biochem Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Yanlei,Wang, Xincheng,Qu, Yongshui,et al. Efficient Dehydration of Fructose to 5-Hydroxymethylfurfural Catalyzed by Heteropolyacid Salts[J]. CATALYSTS,2016,6(4):1. |
| APA | Song, Yanlei,Wang, Xincheng,Qu, Yongshui,Huang, Chongpin,Li, Yingxia,&Chen, Biaohua.(2016).Efficient Dehydration of Fructose to 5-Hydroxymethylfurfural Catalyzed by Heteropolyacid Salts.CATALYSTS,6(4),1. |
| MLA | Song, Yanlei,et al."Efficient Dehydration of Fructose to 5-Hydroxymethylfurfural Catalyzed by Heteropolyacid Salts".CATALYSTS 6.4(2016):1. |
入库方式： OAI收割
来源：过程工程研究所
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