An enhanced approach for biochar preparation using fluidized bed and its application for H2S removal
文献类型：期刊论文
| 作者 | Sun, Yong1,2; Zhang, Jing Ping3; Wen, Chao4; Zhang, Lian5 |
| 刊名 | CHEMICAL ENGINEERING AND PROCESSING
 |
| 出版日期 | 2016-06-01 |
| 卷号 | 104期号:JUNE页码:1-12 |
| 关键词 | Biochar Fluidized bed H2S removal Black liquor |
| ISSN号 | 0255-2701 |
| 英文摘要 | Fluidized bed efficiently intensifies the carbonization step for biochar preparation by significantly reducing carbonization duration down to 6 min at 450 degrees C. The BET specific surface area of the char carbonized at 6 min can reach 60 m(2)/g. The produced porous biochar possesses both micropores and mesopores. The produced biochars are found to be alkaline. The degree of heterogeneity on the surface of biochar is far more than that of commercial activated carbon. The maximum monolayer adsorption capacity from Langmuir model can reach 25 mg/g at room temperature and ambient pressure by using equilibrium isotherm approximation. The maximum sulfur removal can reach 70 mg/g using column dynamic adsorption. The moisture shows a beneficial effect on the adsorption of H2S on biochar. The maximum removal rate and saturation constants were obtained using Mechael's-Menten type equation. The mass transfer diffusivities data indicate the surface diffusion being significant to the effective diffusivity at experimental conditions. The dynamic experimental results indicate a good performance of resultant biochar in H2S removal at room temperature. (C) 2016 Elsevier B.V. All rights reserved. |
| WOS标题词 | Science & Technology ; Technology |
| 类目[WOS] | Energy & Fuels ; Engineering, Chemical |
| 研究领域[WOS] | Energy & Fuels ; Engineering |
| 关键词[WOS] | HYDROGEN-SULFIDE REMOVAL ; FISCHER-TROPSCH SYNTHESIS ; ACTIVATED CARBON ; BLACK LIQUOR ; SURFACE-AREA ; ADSORPTION ; DIOXIDE ; LIGNIN ; PERFORMANCE ; ADSORBENTS |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000375811300001 |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/21055]  |
| 专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
| 作者单位 | 1.Edith Cowan Univ, Sch Engn, 270 Joondalup Dr, Joondalup, WA 6027, Australia 2.CSIRO, Earth Sci & Resources Engn, 26 Dick Perry Ave, Kensington, WA 6151, Australia 3.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 4.NW Univ Xian, Sch Informat Sci & Technol, Xian 710069, Peoples R China 5.Monash Univ, Dept Chem Engn, Clayton, Vic 3800, Australia |
| 推荐引用方式 GB/T 7714 | Sun, Yong,Zhang, Jing Ping,Wen, Chao,et al. An enhanced approach for biochar preparation using fluidized bed and its application for H2S removal[J]. CHEMICAL ENGINEERING AND PROCESSING,2016,104(JUNE):1-12. |
| APA | Sun, Yong,Zhang, Jing Ping,Wen, Chao,&Zhang, Lian.(2016).An enhanced approach for biochar preparation using fluidized bed and its application for H2S removal.CHEMICAL ENGINEERING AND PROCESSING,104(JUNE),1-12. |
| MLA | Sun, Yong,et al."An enhanced approach for biochar preparation using fluidized bed and its application for H2S removal".CHEMICAL ENGINEERING AND PROCESSING 104.JUNE(2016):1-12. |
入库方式： OAI收割
来源：过程工程研究所
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