Electro-catalysis of carbon black or titanium sub-oxide supported Pd-Gd towards formic acid electro-oxidation
文献类型:期刊论文
作者 | He, Nan1,2; Qin, Chuanguang2; Wang, Rumin2; Ma, Shuhui1; Wang, Yi1; Qi, Tao1 |
刊名 | RSC ADVANCES
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出版日期 | 2016 |
卷号 | 6期号:73页码:68989-68996 |
ISSN号 | 2046-2069 |
英文摘要 | Carbon black supported Pd-Gd catalysts (Pd-xGd/C, x is weight percent in catalyst) with different amounts of Gd were prepared by a simultaneous reduction reaction with sodium borohydride in aqueous solution. The structure, morphology and element valence state of these catalysts were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS), respectively. The electro-catalytic performance of these catalysts for formic acid oxidation was investigated using cyclic voltammetry (CV), chronoamperometry (CA) and CO stripping experiments. It is found that the Pd-2.5Gd/C catalyst has a better electro-catalytic activity than the Pd/C catalyst, which can be explained by a bi-functional mechanism. In addition, the higher content of metallic Pd caused by the addition of Gd also contributes to the better catalytic activity of Pd-2.5Gd/C. Based on the good electro-catalytic performance of the Pd-2.5Gd/C, Pd-xGd/Ti4O7 (x stands for weight percentage in whole catalyst) catalysts were also prepared and characterized in the same way. The Pd-2.5Gd/Ti4O7 and Pd-4Gd/Ti4O7 catalysts exhibited better catalytic activities than the Pd-2.5Gd/C catalyst, which mainly results from the further increase of metallic Pd caused by Ti4O7. |
WOS标题词 | Science & Technology ; Physical Sciences |
类目[WOS] | Chemistry, Multidisciplinary |
研究领域[WOS] | Chemistry |
关键词[WOS] | FUEL-CELLS ; ELECTROCATALYTIC ACTIVITY ; GOLD NANOPARTICLES ; ALLOY CATALYSTS ; OXIDATION ; METHANOL ; ETHANOL ; NANOTUBES ; STABILITY ; MEDIA |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000381512600049 |
源URL | [http://ir.ipe.ac.cn/handle/122111/21282] ![]() |
专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 2.Northwestern Polytech Univ, Sch Nat & Appl Sci, Xian 710072, Peoples R China |
推荐引用方式 GB/T 7714 | He, Nan,Qin, Chuanguang,Wang, Rumin,et al. Electro-catalysis of carbon black or titanium sub-oxide supported Pd-Gd towards formic acid electro-oxidation[J]. RSC ADVANCES,2016,6(73):68989-68996. |
APA | He, Nan,Qin, Chuanguang,Wang, Rumin,Ma, Shuhui,Wang, Yi,&Qi, Tao.(2016).Electro-catalysis of carbon black or titanium sub-oxide supported Pd-Gd towards formic acid electro-oxidation.RSC ADVANCES,6(73),68989-68996. |
MLA | He, Nan,et al."Electro-catalysis of carbon black or titanium sub-oxide supported Pd-Gd towards formic acid electro-oxidation".RSC ADVANCES 6.73(2016):68989-68996. |
入库方式: OAI收割
来源:过程工程研究所
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