Substrate-induced adjustment of "slipped" pi-pi stacking: en route to obtain 1D sandwich chain and higher order self-assembly supramolecular structures in solid state
文献类型：期刊论文
| 作者 | Shen, Meng-Jie1; Liang, Tong-Ling2; Song, Yue-Qiang3; Xu, Li-Jin1; Hao, Xiang2; Gong, Han-Yuan4 |
| 刊名 | SUPRAMOLECULAR CHEMISTRY
 |
| 出版日期 | 2017 |
| 卷号 | 29期号:1页码:24-31 |
| 关键词 | Self-assemble 'slipped' pi-pi stacking expanding direction adjustment substrate-induced control selective CO2 absorption |
| 英文摘要 | 'Slipped' pi-pi stacking between flexible macrocycle 1(4+) (cyclo[2](2,6-di(1H-imidazol-1-yl)pyridine) [2](1,4-dimethylene benzene)) and neutral small molecules induce one-dimensional (1D) 'sandwich' chain self-assembly. Unlike most of the reported pi-pi stacking system, the 1D "sandwich" chain expands with the direction parallel to stacking pi surfaces on 1(4+) and that on molecule 2, 3, 4 or 5 (2 = p-xylene, 3 = benzene-1,4-diamine, 4 = 4,4'-bipyridine, 5 = [1,1'-biphenyl]-4,4'-diol). Moreover, the pi-pi stacking modes of 1D self-assembly are seriously small molecule adduct dependent. Combined with the other weak interactions (e.g. intermolecular hydrogen bonding), the new substrate design and control strategy can expand the 1D 'sandwich' chain (e.g. [1(4+center dot)4](n)) into higher order structure (e.g. two-dimensional (2D) network [1(4+)center dot 4 center dot 6](n), 6 = hydroquinone) even in large scale (similar to 280 mg). This 2D network structure, which keeps stable under 423 K, shows highly selective gas absorption of CO2 over N-2. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35087]  |
| 专题 | 化学研究所_分析测试中心 |
| 作者单位 | 1.Renmin Univ China, Dept Chem, Beijing, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing, Peoples R China 3.Qingdao Harbour Vacat & Tech Coll, Dept Informat Engn, Qingdao, Peoples R China 4.Beijing Normal Univ, Coll Chem, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shen, Meng-Jie,Liang, Tong-Ling,Song, Yue-Qiang,et al. Substrate-induced adjustment of "slipped" pi-pi stacking: en route to obtain 1D sandwich chain and higher order self-assembly supramolecular structures in solid state[J]. SUPRAMOLECULAR CHEMISTRY,2017,29(1):24-31. |
| APA | Shen, Meng-Jie,Liang, Tong-Ling,Song, Yue-Qiang,Xu, Li-Jin,Hao, Xiang,&Gong, Han-Yuan.(2017).Substrate-induced adjustment of "slipped" pi-pi stacking: en route to obtain 1D sandwich chain and higher order self-assembly supramolecular structures in solid state.SUPRAMOLECULAR CHEMISTRY,29(1),24-31. |
| MLA | Shen, Meng-Jie,et al."Substrate-induced adjustment of "slipped" pi-pi stacking: en route to obtain 1D sandwich chain and higher order self-assembly supramolecular structures in solid state".SUPRAMOLECULAR CHEMISTRY 29.1(2017):24-31. |
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来源：化学研究所
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