Reversible CO Dissociation of Tricarbonyl Iodide [Fe]-Hydrogenase Models Ligating Acylmethylpyridyl Ligands
文献类型：期刊论文
| 作者 | Hu, Bowen1; Chen, Xiangyang2,3; Gong, Dawei1; Cui, Wen1; Yang, Xinzheng2; Chen, Dafa1 |
| 刊名 | ORGANOMETALLICS
 |
| 出版日期 | 2016-09-12 |
| 卷号 | 35期号:17页码:2993-2998 |
| 英文摘要 | A combined experimental;and computational investigation of the CO dissociation properties of three [Fe]-hydrogenase models, [(2-CH2CO-6-HOC5H3N)Fe(CO)(3)I] (1), [(2-CH2CO-6-MeOC5H3N)Fe(CO)(3)I] (2), and [(2-CH2CO-6-tBuOC(5)H(3)N)Fe(CO)(3)I] (3), shows equilibria of tricarbonyl and dicarbonyl complexes in solution. In CH3CN, 1 transforms to the solvated product [(2;CH2CO-6-HOC5H3N)Fe-(CO)(2)(CH3CN)I] (7). The reactivity of 2 with PPh3 was also explored; giving [(2-CH2CO-6,MeOC5H3N)Fe(CO)(2)(PPh3)I] (8) via, one CO substitution by PPh3. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35256]  |
| 专题 | 化学研究所_分子动态与稳态结构实验室 |
| 作者单位 | 1.Harbin Inst Technol, MIIT Key Lab Crit Mat Technol New Energy Convers, Sch Chem & Chem Engn, Harbin 150001, Heilongjiang, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Inst Chem, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Bowen,Chen, Xiangyang,Gong, Dawei,et al. Reversible CO Dissociation of Tricarbonyl Iodide [Fe]-Hydrogenase Models Ligating Acylmethylpyridyl Ligands[J]. ORGANOMETALLICS,2016,35(17):2993-2998. |
| APA | Hu, Bowen,Chen, Xiangyang,Gong, Dawei,Cui, Wen,Yang, Xinzheng,&Chen, Dafa.(2016).Reversible CO Dissociation of Tricarbonyl Iodide [Fe]-Hydrogenase Models Ligating Acylmethylpyridyl Ligands.ORGANOMETALLICS,35(17),2993-2998. |
| MLA | Hu, Bowen,et al."Reversible CO Dissociation of Tricarbonyl Iodide [Fe]-Hydrogenase Models Ligating Acylmethylpyridyl Ligands".ORGANOMETALLICS 35.17(2016):2993-2998. |
入库方式： OAI收割
来源：化学研究所
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