Surfactant-Free Palladium Nanoparticles Encapsulated in ZIF-8 Hollow Nanospheres for Size-Selective Catalysis in Liquid-Phase Solution
文献类型：期刊论文
| 作者 | Wang, Xiaoshi1,2; Li, Mingyu3; Cao, Changyan1,2; Liu, Chang1,2; Liu, Jian1,2; Zhu, Yanan1,2; Zhang, Sidi1,2; Song, Weiguo1,2 |
| 刊名 | CHEMCATCHEM
 |
| 出版日期 | 2016-10-20 |
| 卷号 | 8期号:20页码:3224-3228 |
| 关键词 | heterogeneous catalysis metal-organic frameworks nanoparticles palladium zeolites |
| 英文摘要 | Encapsulation of surfactant-free Pd nanoparticles (NPs) in the metal-organic framework material ZIF-8 hollow nanospheres was achieved. Pd@ZIF-8 hollow nanospheres showed excellent size-selective catalytic properties in the liquid-phase hydrogenation of olefins. As a result of the uniform pore size of the ZIF-8 shell (apertures of 3.4 angstrom), the catalyst showed high activity for the hydrogenation of 1-hexene (1.9x8.2 angstrom) but very low activity for larger molecules such as cis-cyclooctene (5.3x5.5 angstrom), trans-stilbene (4.2x11.3 angstrom), and triphenylethylene (9.1x9.2 angstrom). Other surfactant-free noble-metal nanoparticles could also be employed to produce NPs@MOFs for catalysis. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35118]  |
| 专题 | 化学研究所_分子纳米结构与纳米技术实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Inst Chem, Lab Mol Nanostruct & Nanotechnol, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Masters Sch, 49 Clinton Ave, Dobbs Ferry, NY 10522 USA |
| 推荐引用方式 GB/T 7714 | Wang, Xiaoshi,Li, Mingyu,Cao, Changyan,et al. Surfactant-Free Palladium Nanoparticles Encapsulated in ZIF-8 Hollow Nanospheres for Size-Selective Catalysis in Liquid-Phase Solution[J]. CHEMCATCHEM,2016,8(20):3224-3228. |
| APA | Wang, Xiaoshi.,Li, Mingyu.,Cao, Changyan.,Liu, Chang.,Liu, Jian.,...&Song, Weiguo.(2016).Surfactant-Free Palladium Nanoparticles Encapsulated in ZIF-8 Hollow Nanospheres for Size-Selective Catalysis in Liquid-Phase Solution.CHEMCATCHEM,8(20),3224-3228. |
| MLA | Wang, Xiaoshi,et al."Surfactant-Free Palladium Nanoparticles Encapsulated in ZIF-8 Hollow Nanospheres for Size-Selective Catalysis in Liquid-Phase Solution".CHEMCATCHEM 8.20(2016):3224-3228. |
入库方式： OAI收割
来源：化学研究所
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