Manganese-Catalyzed ortho-C-H Alkenylation of Aromatic N-H Imidates with Alkynes: Versatile Access to Mono-Alkenylated Aromatic Nitriles
文献类型：期刊论文
| 作者 | Yang, Xiaoxu; Jin, Xiqing; Wang, Congyang |
| 刊名 | ADVANCED SYNTHESIS & CATALYSIS
 |
| 出版日期 | 2016-07-28 |
| 卷号 | 358期号:15页码:2436-2442 |
| 关键词 | alkynes C-H activation homogeneous catalysis manganese nitriles |
| 英文摘要 | So far, the direct C-H alkenylation of aromatic nitriles with alkynes has not been achieved. Herein, we discribe the first manganese-catalyzed C-H alkenylation of aromatic N-H imidates to access mono-alkenylated aromatic nitriles. The reaction is accelerated by the presence of a catalytic amount of sodium pivalate. This protocol is also highlighted by the simple catalytic system, good compatibility of functional groups, and excellent mono-/dialkenylation selectivity as well as E/Z stereoselectivity. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35265]  |
| 专题 | 化学研究所_分子识别与功能实验室 |
| 作者单位 | Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Xiaoxu,Jin, Xiqing,Wang, Congyang. Manganese-Catalyzed ortho-C-H Alkenylation of Aromatic N-H Imidates with Alkynes: Versatile Access to Mono-Alkenylated Aromatic Nitriles[J]. ADVANCED SYNTHESIS & CATALYSIS,2016,358(15):2436-2442. |
| APA | Yang, Xiaoxu,Jin, Xiqing,&Wang, Congyang.(2016).Manganese-Catalyzed ortho-C-H Alkenylation of Aromatic N-H Imidates with Alkynes: Versatile Access to Mono-Alkenylated Aromatic Nitriles.ADVANCED SYNTHESIS & CATALYSIS,358(15),2436-2442. |
| MLA | Yang, Xiaoxu,et al."Manganese-Catalyzed ortho-C-H Alkenylation of Aromatic N-H Imidates with Alkynes: Versatile Access to Mono-Alkenylated Aromatic Nitriles".ADVANCED SYNTHESIS & CATALYSIS 358.15(2016):2436-2442. |
入库方式： OAI收割
来源：化学研究所
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