Frustratingly synergic effect of cobalt-nickel heterometallic precatalysts on ethylene reactivity: the cobalt and its heteronickel complexes bearing 2-methyl-2,4-bis(6-aryliminopyridin-2-yl)-1H-1,5-benzodiazepines
文献类型：期刊论文
| 作者 | Zhang, Shu1,2; Xing, Qifeng1,2; Sun, Wen-Hua1,2,3
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| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2016 |
| 卷号 | 6期号:76页码:72170-72176 |
| 英文摘要 | A series of 2-methyl-2,4-bis(6-aryliminopyridin-2-yl)-1H-1,5-benzodiazepines were reacted with cobalt chloride to form their corresponding cobalt complexes, which were further reacted with nickel chloride to form their binuclear heteronickel complexes. One of the representative cobalt-nickel complexes was unambiguously confirmed using single-crystal X-ray diffraction. Generally all mononuclear cobalt complexes and binuclear cobalt-nickel complexes showed good activities towards ethylene reactivity (oligomerization and polymerization), however, the mononuclear cobalt complexes showed much higher activities than the binuclear cobalt-nickel analogues, and this is described as the frustratingly synergic effect of heterometallic complexes in ethylene oligomerization. In addition, the obtained oligomers sometimes followed a Poisson distribution. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35316]  |
| 专题 | 化学研究所_工程塑料实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Shu,Xing, Qifeng,Sun, Wen-Hua. Frustratingly synergic effect of cobalt-nickel heterometallic precatalysts on ethylene reactivity: the cobalt and its heteronickel complexes bearing 2-methyl-2,4-bis(6-aryliminopyridin-2-yl)-1H-1,5-benzodiazepines[J]. RSC ADVANCES,2016,6(76):72170-72176. |
| APA | Zhang, Shu,Xing, Qifeng,&Sun, Wen-Hua.(2016).Frustratingly synergic effect of cobalt-nickel heterometallic precatalysts on ethylene reactivity: the cobalt and its heteronickel complexes bearing 2-methyl-2,4-bis(6-aryliminopyridin-2-yl)-1H-1,5-benzodiazepines.RSC ADVANCES,6(76),72170-72176. |
| MLA | Zhang, Shu,et al."Frustratingly synergic effect of cobalt-nickel heterometallic precatalysts on ethylene reactivity: the cobalt and its heteronickel complexes bearing 2-methyl-2,4-bis(6-aryliminopyridin-2-yl)-1H-1,5-benzodiazepines".RSC ADVANCES 6.76(2016):72170-72176. |
入库方式： OAI收割
来源：化学研究所
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