Transition from a Metal-Localized Mixed-Valence Compound to a Fully Delocalized and Bridge-Biased Electrophore in a Ruthenium-Amine-Ruthenium Tricenter System
文献类型：期刊论文
| 作者 | Tang, Jian-Hong1,2; Shao, Jiang-Yang1; He, Yan-Qin1; Wu, Si-Hai1; Yao, Jiannian1,2; Zhong, Yu-Wu1,2 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2016-07-18 |
| 卷号 | 22期号:30页码:10341-10345 |
| 关键词 | density functional calculations electrochemistry electron transfer mixed-valence compounds ruthenium |
| 英文摘要 | A series of cyclometalated diruthenium complexes with a redox-active amine bridge were synthesized. Depending on the terminal ligands of the ruthenium components and the substituent on the amine unit, the one-electron-oxidized state can be either in the form of a weakly or strongly coupled mixed-valence diruthenium complex, a fully charge-delocalized three-center system, or a bridge-biased electrophore. This transition among different electronic forms was supported by electrochemistry, near-infrared absorption, electron paramagnetic resonance, and density functional theory analysis. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35208]  |
| 专题 | 化学研究所_光化学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang, Jian-Hong,Shao, Jiang-Yang,He, Yan-Qin,et al. Transition from a Metal-Localized Mixed-Valence Compound to a Fully Delocalized and Bridge-Biased Electrophore in a Ruthenium-Amine-Ruthenium Tricenter System[J]. CHEMISTRY-A EUROPEAN JOURNAL,2016,22(30):10341-10345. |
| APA | Tang, Jian-Hong,Shao, Jiang-Yang,He, Yan-Qin,Wu, Si-Hai,Yao, Jiannian,&Zhong, Yu-Wu.(2016).Transition from a Metal-Localized Mixed-Valence Compound to a Fully Delocalized and Bridge-Biased Electrophore in a Ruthenium-Amine-Ruthenium Tricenter System.CHEMISTRY-A EUROPEAN JOURNAL,22(30),10341-10345. |
| MLA | Tang, Jian-Hong,et al."Transition from a Metal-Localized Mixed-Valence Compound to a Fully Delocalized and Bridge-Biased Electrophore in a Ruthenium-Amine-Ruthenium Tricenter System".CHEMISTRY-A EUROPEAN JOURNAL 22.30(2016):10341-10345. |
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来源：化学研究所
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