A homoleptic, all-alkynyl-stabilized highly luminescent Au8Ag8 cluster with a single crystal X-ray structure
文献类型：期刊论文
| 作者 | Zhang, Rui1; Zhao, Chongyang2; Li, Xiumin1; Zhang, Zongyao1; Ai, Xicheng1; Chen, Hui2; Cao, Rui1,3 |
| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2016-08-28 |
| 卷号 | 45期号:32页码:12772-12778 |
| 英文摘要 | A homoleptic, all-alkynyl-stabilized [Au8Ag8(ArC C)(16)] (1, Ar = 3,5-di-tert-butylphenyl) cluster was synthesized and characterized with a single crystal X-ray structure. Reactions of 3,5-di-tert-butyl-phenylacetylene with Ag(I) and Au(I) gave [Ag(ArC C)](n) and Au(PPh3)(ArC C), respectively, where both have unusually high solubility in nonpolar organic solvents. In addition to drastically increased solubility, the two bulky tert-butyl substituents on the phenyl ring can confine the metal core to a certain size by preventing infinite aggregation of d(10) metals. This feature makes the isolation of an all-alkynyl-stabilized Au-Ag cluster possible. Complex 1 is intensely luminescent with a very high quantum yield of 0.67 in solution at room temperature. Theoretical studies offered valuable insights into the intriguing photophysical properties, and revealed the significant role of metal-alkynyl bond interactions and enhanced molecular rigidity provided by tert-butyl groups. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35234]  |
| 专题 | 化学研究所_光化学实验室 |
| 作者单位 | 1.Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China 2.Chinese Acad Sci, BNLMS, Inst Chem, Key Lab Photochem, Beijing 100190, Peoples R China 3.Shaanxi Normal Univ, Sch Chem & Chem Engn, Xian 710119, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Rui,Zhao, Chongyang,Li, Xiumin,et al. A homoleptic, all-alkynyl-stabilized highly luminescent Au8Ag8 cluster with a single crystal X-ray structure[J]. DALTON TRANSACTIONS,2016,45(32):12772-12778. |
| APA | Zhang, Rui.,Zhao, Chongyang.,Li, Xiumin.,Zhang, Zongyao.,Ai, Xicheng.,...&Cao, Rui.(2016).A homoleptic, all-alkynyl-stabilized highly luminescent Au8Ag8 cluster with a single crystal X-ray structure.DALTON TRANSACTIONS,45(32),12772-12778. |
| MLA | Zhang, Rui,et al."A homoleptic, all-alkynyl-stabilized highly luminescent Au8Ag8 cluster with a single crystal X-ray structure".DALTON TRANSACTIONS 45.32(2016):12772-12778. |
入库方式： OAI收割
来源：化学研究所
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