Hierarchically Mesoporous o-Hydroxyazobenzene Polymers: Synthesis and Their Applications in CO2 Capture and Conversion
文献类型：期刊论文
| 作者 | Ji, Guipeng1,2; Yang, Zhenzhen1; Zhang, Hongye1; Zhao, Yanfei1; Yu, Bo1; Ma, Zhishuang1,2; Liu, Zhimin1,2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2016-08-08 |
| 卷号 | 55期号:33页码:9684-9688 |
| 关键词 | CO2 conversion diazo-coupling reaction o-hydroxyazobenzene porous organic polymers |
| 英文摘要 | The synthesis of hierarchically mesoporous polymers with multiple functionalities is challenging. Herein we reported a template-free strategy for synthesis of phenolic azo-polymers with hierarchical porous structures based on diazo-coupling reaction in aqueous solution under mild conditions. The resultant polymers have surface areas up to 593 m(2) g(-1) with the mesopore ratio of > 80%, and a good ability to complex with metal ions, such as Cu2+, Zn2+, Ni2+, achieving a metal loading up to 26.24 wt%. Moreover, the polymers complexed with Zn showed excellent performance for catalyzing the reaction of CO2 with epoxide, affording a TOF of 2570 h(-1) in the presence of tetrabutyl ammonium bromide (7.2 mol%). The polymer complexed with Cu could catalyze the oxidation of alcohol with high efficiency. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35314]  |
| 专题 | 化学研究所_胶体、界面与化学热力学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Colloid Interface & Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ji, Guipeng,Yang, Zhenzhen,Zhang, Hongye,et al. Hierarchically Mesoporous o-Hydroxyazobenzene Polymers: Synthesis and Their Applications in CO2 Capture and Conversion[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2016,55(33):9684-9688. |
| APA | Ji, Guipeng.,Yang, Zhenzhen.,Zhang, Hongye.,Zhao, Yanfei.,Yu, Bo.,...&Liu, Zhimin.(2016).Hierarchically Mesoporous o-Hydroxyazobenzene Polymers: Synthesis and Their Applications in CO2 Capture and Conversion.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,55(33),9684-9688. |
| MLA | Ji, Guipeng,et al."Hierarchically Mesoporous o-Hydroxyazobenzene Polymers: Synthesis and Their Applications in CO2 Capture and Conversion".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 55.33(2016):9684-9688. |
入库方式： OAI收割
来源：化学研究所
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