Z-Selective Synthesis of gamma,delta-Unsaturated Ketones via Pd-Catalyzed Ring Opening of 2-Alkylenecyclobutanones with Arylboronic Acids
文献类型：期刊论文
| 作者 | Zhou, Yao1; Rao, Changqing1; Song, Qinling1,2 |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2016-08-19 |
| 卷号 | 18期号:16页码:4000-4003 |
| 英文摘要 | Pd-catalyzed 1,2-addition (instead of 1,4-addition) of arylboronic acids to 2-alkylenecyclobutanones followed by beta-carbon elimination from the resulting palladium cyclobutanolates to afford gamma,delta-unsaturated ketones was developed. The desired gamma,delta-unsaturated ketones were obtained in good to excellent yields with Z/E selectivities of up to >99:1 and a broad spectrum of functional group tolerability. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35233]  |
| 专题 | 化学研究所_其它 |
| 作者单位 | 1.Huaqiao Univ, Inst Next Generat Matter Transformat, Coll Chem Engn, Coll Mat Sci & Engn, 668 Jimei Blvd, Xiamen 361021, Fujian, Peoples R China 2.Inst Chem, Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Yao,Rao, Changqing,Song, Qinling. Z-Selective Synthesis of gamma,delta-Unsaturated Ketones via Pd-Catalyzed Ring Opening of 2-Alkylenecyclobutanones with Arylboronic Acids[J]. ORGANIC LETTERS,2016,18(16):4000-4003. |
| APA | Zhou, Yao,Rao, Changqing,&Song, Qinling.(2016).Z-Selective Synthesis of gamma,delta-Unsaturated Ketones via Pd-Catalyzed Ring Opening of 2-Alkylenecyclobutanones with Arylboronic Acids.ORGANIC LETTERS,18(16),4000-4003. |
| MLA | Zhou, Yao,et al."Z-Selective Synthesis of gamma,delta-Unsaturated Ketones via Pd-Catalyzed Ring Opening of 2-Alkylenecyclobutanones with Arylboronic Acids".ORGANIC LETTERS 18.16(2016):4000-4003. |
入库方式： OAI收割
来源：化学研究所
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