Diboron-Assisted Palladium-Catalyzed Transfer Hydrogenation of N-Heteroaromatics with Water as Hydrogen Donor and Solvent
文献类型：期刊论文
| 作者 | Xuan, Qingqing1; Song, Qiuling1,2 |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2016-09-02 |
| 卷号 | 18期号:17页码:4250-4253 |
| 英文摘要 | A Pd-catalyzed transfer hydrogenation of various N-heteroaromatic compounds with B(2)pin(2) as a mediator and environmentally benign water as both solvent and hydrogen donor has been disclosed. This reaction proceeded under ambient temperature with a broad range of N-heteroaromatic compounds among which imidazo [1,2-alpha]pyridine derivatives were for the first time selectively reduced to 5,6,7,8-tetrahydroimidazo[1,2-alpha]pyridines, which are the core structural motifs of an inhibitor of human O-GlcNAcase. Mechanistic studies suggested that the new protons products are from water and Pd-H might be the key intermediate with B(2)pin(2) as the H2O activator. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35267]  |
| 专题 | 化学研究所_其它 |
| 作者单位 | 1.Huaqiao Univ, Coll Chem Engn, Inst Next Generat Matter Transformat, 668 Jimei Blvd, Xiamen 361021, Fujian, Peoples R China 2.Chinese Acad Sci, Inst Chem, Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xuan, Qingqing,Song, Qiuling. Diboron-Assisted Palladium-Catalyzed Transfer Hydrogenation of N-Heteroaromatics with Water as Hydrogen Donor and Solvent[J]. ORGANIC LETTERS,2016,18(17):4250-4253. |
| APA | Xuan, Qingqing,&Song, Qiuling.(2016).Diboron-Assisted Palladium-Catalyzed Transfer Hydrogenation of N-Heteroaromatics with Water as Hydrogen Donor and Solvent.ORGANIC LETTERS,18(17),4250-4253. |
| MLA | Xuan, Qingqing,et al."Diboron-Assisted Palladium-Catalyzed Transfer Hydrogenation of N-Heteroaromatics with Water as Hydrogen Donor and Solvent".ORGANIC LETTERS 18.17(2016):4250-4253. |
入库方式： OAI收割
来源：化学研究所
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