Three-Bladed Rylene Propellers with Three-Dimensional Network Assembly for Organic Electronics
文献类型：期刊论文
| 作者 | Meng, Dong1,7; Fu, Huiting1,2,7; Xiao, Chengyi1,7; Meng, Xiangyi5; Winands, Thorsten3,4; Ma, Wei5; Wei, Wei6; Fan, Bingbing2; Huo, Lijun2; Doltsinis, Nikos L.3,4 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2016-08-17 |
| 卷号 | 138期号:32页码:10184-10190 |
| 英文摘要 | Two kinds of conjugated C-3-syrnmettic perylene dyes, namely, triperylene hexaimides (TPH) and selenium annulated triperylene hexairnides: (TPH-Se); are efficiently synthesized. Both TPH and TPH-Se have broad and strong absorption in the region 300-600 nm together with suitable LUMO levels of about -3.8 eV. Single-crystal X-ray difftaction studies show that TPH displays an extremely twisted three bladed propeller configuration and a unique 3D network assembly in which three PBI subunits in one TPH molecule have strong pi-pi intermolecular interactions with PBI subunits in neighboring molecules. The integration of selenophene to TPH endows TPH-Se with a More distorted propeller configuration and a more compact 3D network assembly due to the Se center dot center dot center dot O interactions. A single-crystal transistor confirms that both TPH and TPH-Se possess good electron-transport ability. TPH and TPH-Se acceptor-based solar cells show high power conversion efficiency of 8.28% and 9.28%, respectively, which mainly results from the combined properties of broad and strong absorption ability, appropriate LUMO level, desirable aggregation, high electron mobility, and good film morphology with the polymer donor. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35225]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Key Lab Organ Solids, Beijing 100190, Peoples R China 2.Beihang Univ, Heeger Beijing Res & Dev Ctr, Sch Chem & Environm, Beijing 100191, Peoples R China 3.Univ Munster, Inst Solid State Theory, Wilhelm Klemm Str 10, D-48149 Munster, Germany 4.Univ Munster, Ctr Multiscale Theory & Computat, Wilhelm Klemm Str 10, D-48149 Munster, Germany 5.Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China 6.Capital Normal Univ, Dept Chem, Beijing 100049, Peoples R China 7.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Meng, Dong,Fu, Huiting,Xiao, Chengyi,et al. Three-Bladed Rylene Propellers with Three-Dimensional Network Assembly for Organic Electronics[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2016,138(32):10184-10190. |
| APA | Meng, Dong.,Fu, Huiting.,Xiao, Chengyi.,Meng, Xiangyi.,Winands, Thorsten.,...&Wang, Zhaohui.(2016).Three-Bladed Rylene Propellers with Three-Dimensional Network Assembly for Organic Electronics.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,138(32),10184-10190. |
| MLA | Meng, Dong,et al."Three-Bladed Rylene Propellers with Three-Dimensional Network Assembly for Organic Electronics".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 138.32(2016):10184-10190. |
入库方式： OAI收割
来源：化学研究所
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