Impact of the alkyl side chain position on the photovoltaic properties of solution-processable organic molecule donor materials
文献类型：期刊论文
| 作者 | Zhang, J.1; Zhu, X. W.2; He, C.3; Bin, H. J.3; Xue, L. W.3; Wang, W. G.3; Yang, Y. K.3; Yuan, N. Y.1; Ding, J. N.1; Wei, Z. X.2 |
| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
 |
| 出版日期 | 2016 |
| 卷号 | 4期号:30页码:11747-11753 |
| 英文摘要 | Two new A-D-A structured organic molecules with bithienyl-substituted benzodithiophene (BDT) as the core and donor unit, indenedione (ID) as the end group and acceptor unit, 3,3 ''-dihexyl-2,2':5',2 ''-terthiophene (3T(3-Hex)) or 4,4 ''-dihexyl-2,2':5',2 ''-terthiophene (3T(4-Hex)) as the pi bridge, BDT-3T(3-Hex)-ID and BDT-3T(4-Hex)-ID, were designed and synthesized. The two compounds with the alkyl side chains at different positions in the pi bridge backbone which are applied in solution-processable organic solar cells (OSCs) as donor materials have the same molecular weight and a similar structure, but exhibit different optical and photovoltaic properties. The BDT-3T(4-Hex)-ID film shows a broad absorption band from 400 nm to 750 nm with an absorption peak about 20 nm red-shifted compared to that of BDT-3T( 3-Hex)-ID in solution, benefitting from the outward alkyl side chain in its structure. The power conversion efficiency (PCE) of the solution-processed OSC based on a blend of BDT-3T(4-Hex)-ID and PC71BM (1.25 : 1, w/w) reached 6.55% with a J(sc) of 10.54 mA cm(-2), a V-oc of 0.87 V and a FF of 71.4%, under the illumination of AM 1.5, 100 mW cm(-2). In comparison, the PCE of the OSC based on BDT-3T( 3-Hex)-ID as the donor is 1.06% under the same experimental conditions. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35227]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Changzhou Univ, Sch Mat Sci & Engn, Jiangsu Collaborat Innovat Ctr Photovolta Sci & E, Changzhou 213164, Jiangsu, Peoples R China 2.Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, J.,Zhu, X. W.,He, C.,et al. Impact of the alkyl side chain position on the photovoltaic properties of solution-processable organic molecule donor materials[J]. JOURNAL OF MATERIALS CHEMISTRY A,2016,4(30):11747-11753. |
| APA | Zhang, J..,Zhu, X. W..,He, C..,Bin, H. J..,Xue, L. W..,...&Li, Y. F..(2016).Impact of the alkyl side chain position on the photovoltaic properties of solution-processable organic molecule donor materials.JOURNAL OF MATERIALS CHEMISTRY A,4(30),11747-11753. |
| MLA | Zhang, J.,et al."Impact of the alkyl side chain position on the photovoltaic properties of solution-processable organic molecule donor materials".JOURNAL OF MATERIALS CHEMISTRY A 4.30(2016):11747-11753. |
入库方式： OAI收割
来源：化学研究所
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