Effect of Alkyl Side Chains of Conjugated Polymer Donors on the Device Performance of Non-Fullerene Solar Cells
文献类型:期刊论文
作者 | Xia, Dongdong1; Wu, Yang2; Wang, Qiang3,4; Zhang, Andong1; Li, Cheng1; Lin, Yuze5; Colberts, Fallon J. M.3,4; van Franeker, Jacobus J.3,4; Janssen, Rene A. J.3,4; Zhan, Xiaowei5 |
刊名 | MACROMOLECULES
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出版日期 | 2016-09-13 |
卷号 | 49期号:17页码:6445-6454 |
英文摘要 | The influence of the chemical: structure of conjugated polymers on the nanophase separation and device performance in fullerene-based solar cells has been widely studied, while this is, less investigated in non-fullerene solar cells. In this work, we design three conjugated polymers With-different length of side chains, and we find that the length of side chains has little influence on the quantum efficiencies of non-fullerene solar cells. As a comparison, the length of side chains has a significant effect on the quantum efficiencies of fullerene-based solar cells. This indicates that morphology of the blended thin films in non-fullerene solar, cells is rather independent of the length of the donor side chains; and the mechanism for morphology evolution in the non-fullerene system is completely different from that in the fullerene system. Our conclusion is confirmed by a variety of advanced characterization techniques. The studies reveal that in blended thin films based on the non-fullerene material the donor polymers with different side chains have a Similar coherence length of pi-pi stacking, crystal size and domain purity, giving rise-to similar internal quantum efficiency and power conversion efficiency of the solar cells. |
收录类别 | SCI |
语种 | 英语 |
源URL | [http://ir.iccas.ac.cn/handle/121111/35254] ![]() |
专题 | 化学研究所_有机固体实验室 |
作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing 10090, Peoples R China 2.Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China 3.Eindhoven Univ Technol, Mol Mat & Nanosyst, POB 513, NL-5600 MB Eindhoven, Netherlands 4.Eindhoven Univ Technol, Inst Complex Mol Syst, POB 513, NL-5600 MB Eindhoven, Netherlands 5.Peking Univ, Coll Engn, Dept Mat Sci & Engn, Beijing 100871, Peoples R China 6.Tech Univ Dresden, Inst Angew Photophys, George Bahr Str 1, D-01069 Dresden, Germany |
推荐引用方式 GB/T 7714 | Xia, Dongdong,Wu, Yang,Wang, Qiang,et al. Effect of Alkyl Side Chains of Conjugated Polymer Donors on the Device Performance of Non-Fullerene Solar Cells[J]. MACROMOLECULES,2016,49(17):6445-6454. |
APA | Xia, Dongdong.,Wu, Yang.,Wang, Qiang.,Zhang, Andong.,Li, Cheng.,...&Li, Weiwei.(2016).Effect of Alkyl Side Chains of Conjugated Polymer Donors on the Device Performance of Non-Fullerene Solar Cells.MACROMOLECULES,49(17),6445-6454. |
MLA | Xia, Dongdong,et al."Effect of Alkyl Side Chains of Conjugated Polymer Donors on the Device Performance of Non-Fullerene Solar Cells".MACROMOLECULES 49.17(2016):6445-6454. |
入库方式: OAI收割
来源:化学研究所
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