中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
pH-Responsive nano sensing valve with self-monitoring state property based on hydrophobicity switching

文献类型:期刊论文

作者Jiao, Xiangyu1; Li, Yanan2; Li, Fengyu2; Wang, Wenqian1; Wen, Yongqiang1; Song, Yanlin2; Zhang, Xueji1
刊名RSC ADVANCES
出版日期2016
卷号6期号:57页码:52292-52299
英文摘要Nano valves have been used in functional porous materials to control molecular transport by changing their properties in response to external stimuli. But most of them are limited by the blocking units and cannot show their state by themselves. Herein, pH switchable nano valves were constructed using mesoporous inverse opal photonic crystal, which realized free-blockage nano valves and achieved the monitoring of the state of the valve by the naked eye without an external indicator. The nano valves were modified by phenylamine groups, which has a convertible hydrophobic/hydrophilic property between deprotonation and protonation. The valves were hydrophobic enough to prevent solution passing through at pH 7.0, and meanwhile a green color was presented. With the decrease of the pH value of the solution, the valves became open and presented a yellow to red color because of the protonation of phenylamine groups followed by the invasion of solution. Thus, in this study not only a free-blockage valve but also nano sensing valve was constructed. We believe that our studies provide new insights into photonic crystal sensors and nano sensing valve.
收录类别SCI
语种英语
源URL[http://ir.iccas.ac.cn/handle/121111/35366]  
专题化学研究所_有机固体实验室
作者单位1.Univ Sci & Technol Beijing, Sch Chem & Biol Engn, Res Ctr Bioengn & Sensing Technol, Beijing 100083, Peoples R China
2.Chinese Acad Sci, Inst Chem, BNLMS, Key Lab Green Printing,Key Lab Organ Solids, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Jiao, Xiangyu,Li, Yanan,Li, Fengyu,et al. pH-Responsive nano sensing valve with self-monitoring state property based on hydrophobicity switching[J]. RSC ADVANCES,2016,6(57):52292-52299.
APA Jiao, Xiangyu.,Li, Yanan.,Li, Fengyu.,Wang, Wenqian.,Wen, Yongqiang.,...&Zhang, Xueji.(2016).pH-Responsive nano sensing valve with self-monitoring state property based on hydrophobicity switching.RSC ADVANCES,6(57),52292-52299.
MLA Jiao, Xiangyu,et al."pH-Responsive nano sensing valve with self-monitoring state property based on hydrophobicity switching".RSC ADVANCES 6.57(2016):52292-52299.

入库方式: OAI收割

来源:化学研究所

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