A colour-tunable chiral AIEgen: reversible coordination, enantiomer discrimination and morphology visualization
文献类型：期刊论文
| 作者 | Roose, Jesse1,2,3; Leung, Anakin Chun Sing1,2,3; Wang, Jia4; Peng, Qian5; Sung, Herman H. -Y.3; Williams, Ian Duncan3; Tang, Ben Zhong1,2,3,4 |
| 刊名 | CHEMICAL SCIENCE
 |
| 出版日期 | 2016 |
| 卷号 | 7期号:9页码:6106-6114 |
| 英文摘要 | We present a conceptually new approach to synthesise a boron-containing Aggregation-Induced Emissive Luminogen (AIEgen) with a chiral chromophore. An intramolecular N-B coordinating bond results in a low-energy transition that renders the material red-emissive in a solid state. By competitive binding of nucleophiles to the boron atom, this bond is replaced in favour of an intermolecular coordinating bond, which results in a tremendous blue-shift in both the absorption and emission. A supportive DFT computation elucidates that a breakage of the intramolecular N-B coordinating bond causes a tremendous loss of conjugation in the LUMO, resulting in a larger energy gap. Owing to the fact that our scaffold is intrinsically chiral and Lewis-acidic, we demonstrate how our AIEgen discriminates between two pairs of enantiomers in a simple UV-vis measurement. Furthermore, the binding capabilities are exploited to stain polymer blends that comprised a non-coordinating and a Lewis-basic polymer. The red fluorescence that originates only from domains of the non-coordinating polymer is conveniently detected by a fluorescence microscope. Thus, compared to current analytical methods, we present a cheaper and faster methodology to study the micro-morphologies of certain polymer blends. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/35381]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.HKUST Shenzhen Res Inst, 9 Yuexing 1st RD,South Area,High Tech Park, Shenzhen 518057, Peoples R China 2.Hong Kong Univ Sci & Technol, Inst Adv Study,Dept Chem,Hong Kong Branch, Inst Mol Funct Mat,Div Biomed Engn,Div Life Sci, Chinese Natl Engn Res Ctr Tissue Restorat & Recon, Kowloon, Hong Kong, Peoples R China 3.Hong Kong Univ Sci & Technol, State Key Lab Mol Neurosci, Kowloon, Hong Kong, Peoples R China 4.South China Univ Technol, State Key Lab Luminescent Mat & Devices, SCUT HKUST Joint Res Lab, Guangdong Innovat Res Team, Guangzhou 510640, Guangdong, Peoples R China 5.Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Roose, Jesse,Leung, Anakin Chun Sing,Wang, Jia,et al. A colour-tunable chiral AIEgen: reversible coordination, enantiomer discrimination and morphology visualization[J]. CHEMICAL SCIENCE,2016,7(9):6106-6114. |
| APA | Roose, Jesse.,Leung, Anakin Chun Sing.,Wang, Jia.,Peng, Qian.,Sung, Herman H. -Y..,...&Tang, Ben Zhong.(2016).A colour-tunable chiral AIEgen: reversible coordination, enantiomer discrimination and morphology visualization.CHEMICAL SCIENCE,7(9),6106-6114. |
| MLA | Roose, Jesse,et al."A colour-tunable chiral AIEgen: reversible coordination, enantiomer discrimination and morphology visualization".CHEMICAL SCIENCE 7.9(2016):6106-6114. |
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来源：化学研究所
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