Influence of Al3+ and P5+ ion contents on the valence state of Yb3+ ions and the dispersion effect of Al3+ and P5+ ions on Yb3+ ions in silica glass
文献类型：期刊论文
| 作者 | Wang, S.; Lou, F.; Yu, C.; Zhou, Q.; Wang, M.; Feng, S.; Chen, D.; Hu, L.; Chen, W.; Guzik, M. |
| 刊名 | j. mater. chem. c
 |
| 出版日期 | 2014 |
| 卷号 | 2期号:22页码:4406 |
| 关键词 | PHOTONIC CRYSTAL FIBER COOPERATIVE LUMINESCENCE SPECTROSCOPIC PROPERTIES YTTERBIUM LASERS FLUORESCENCE FABRICATION ABSORPTION EMISSION OXYGEN |
| 通讯作者 | wang, s (reprint author), chinese acad sci, shanghai inst opt & fine mech, 390 qinghe rd, shanghai 201800, peoples r china. |
| 英文摘要 | three series of yb3+-doped silica glasses containing different amounts of al2o3 and p2o5 were prepared successfully by using a sol-gel method. absorption, excitation and fluorescence spectra of yb2+ ions in these silica glasses as well as x-ray photoelectron spectra (xps) of yb4d were recorded and analysed systematically. it is found out that the addition of al3+ or p5+ ions has great influence on the redox state of ytterbium ions. with increasing al3+ ion contents in these silica glasses, more trivalent yb3+ ions are reduced to divalent yb2+. in contrast, the increase of p5+ ion contents greatly promotes divalent yb2+ ions to be oxidized to trivalent yb3+. the possible redox mechanisms have been explored and discussed in detail. the influence of al3+ and p5+ ion contents on the near-infrared luminescence intensity of yb3+ ions and cooperative luminescence of yb3+ ion pairs was also discussed. both the near-infrared luminescence intensity of yb3+ ions and cooperative luminescence of yb3+ ion pairs decrease gradually with increasing al3+ and p5+ ion contents. the decrease of cooperative luminescence of yb3+ ion pairs indicates a good dispersion effect of al3+ and p5+ ions on yb3+ ions in yb3+-doped silica glass. the results are useful for optimization of fabrication of the high quality yb3+-doped silica fiber by the composite design of yb-al-p co-doped silica glass. |
| 收录类别 | SCI |
| 语种 | 英语 |
| 版本 | 出版稿 |
| 源URL | [http://ir.siom.ac.cn/handle/181231/13126]  |
| 专题 | 上海光学精密机械研究所_高功率激光单元技术研发中心 |
| 作者单位 | 1.[Wang, S. 2.Lou, F. 3.Yu, C. 4.Zhou, Q. 5.Wang, M. 6.Feng, S. 7.Chen, D. 8.Hu, L. 9.Chen, W.] Chinese Acad Sci, Shanghai Inst Opt & Fine Mech, Shanghai 201800, Peoples R China 10.[Wang, S. |
| 推荐引用方式 GB/T 7714 | Wang, S.,Lou, F.,Yu, C.,et al. Influence of Al3+ and P5+ ion contents on the valence state of Yb3+ ions and the dispersion effect of Al3+ and P5+ ions on Yb3+ ions in silica glass[J]. j. mater. chem. c,2014,2(22):4406. |
| APA | Wang, S..,Lou, F..,Yu, C..,Zhou, Q..,Wang, M..,...&Boulon, G..(2014).Influence of Al3+ and P5+ ion contents on the valence state of Yb3+ ions and the dispersion effect of Al3+ and P5+ ions on Yb3+ ions in silica glass.j. mater. chem. c,2(22),4406. |
| MLA | Wang, S.,et al."Influence of Al3+ and P5+ ion contents on the valence state of Yb3+ ions and the dispersion effect of Al3+ and P5+ ions on Yb3+ ions in silica glass".j. mater. chem. c 2.22(2014):4406. |
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来源：上海光学精密机械研究所
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